4.3 Article

Electrochemical Properties of Rutile TiO2 Nanorod Array in Lithium Hydroxide Solution

Journal

NANOSCALE RESEARCH LETTERS
Volume 11, Issue -, Pages -

Publisher

SPRINGEROPEN
DOI: 10.1186/s11671-016-1662-8

Keywords

Aqueous Li-ion batteries; Anode; Rutile TiO2; Nanorod array

Funding

  1. National Natural Science Foundation of China [21203134, 21671200]
  2. Prospective Project of Industry-University-Research Institution of Jiangsu Province, China [BY2014059-13]

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In this paper, rutile TiO2 nanorod arrays are fabricated by a template-free method and proposed as a promising anode for aqueous Li-ion battery. The as-prepared TiO2 nanorod arrays exhibited reversible Li-ion insertion/extraction ability in aqueous LiOH electrolyte. Moreover, galvanostatic charge/discharge test results demonstrated that the reversible capacity of TiO2 nanorods could reach about 39.7 mC cm(-2), and 93.8 % of initial capacity was maintained after 600 cycles at a current density of 1 mA cm(-2) (= 240 C rate), indicating excellent cycling stability and rate capability.

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