4.6 Article

Dry-Printing Conductive Circuit Traces on Water-Soluble Papers

Journal

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 11, Issue 46, Pages 16407-16416

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.3c02575

Keywords

papertronics; printed electronics; additivenanomanufacturing; dry printing; biodegradable electronics

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Printed electronics are gaining significant interest due to their flexibility in design and low manufacturing cost. However, conventional substrates pose environmental challenges. This study introduces a dry printing process for printing conductive silver lines on biodegradable papers, providing a potential solution for eco-friendly printed electronics and sensors.
Printed electronics are gaining significant interest due to their design flexibility, low fabrication cost, and rapid design-to-manufacturing turnaround. Conventional substrates for printed electronics are often based on nonbiodegradable polymers such as polyimide that pose high environmental challenges by creating massive e-waste and pollution. As the demand for printed electronics and sensors increases, the ability to print such devices on biodegradable substrates can provide a solution to such environmental problems. However, current printing technologies are based on liquids and inks that are incompatible with biodegradable substrates, such as paper. Here, we present a dry-printing process, namely, a dry additive nanomanufacturing (Dry-ANM) technique, for printing conductive silver lines and patterns on biodegradable papers for flexible hybrid papertronics. Pure and dry nanoparticles are generated by pulsed laser ablation of a silver target that is then transported through a nozzle and directed onto paper substrates, where they are deposited and laser-sintered in real time to form the desired pattern without damaging the paper. The effects of different printing parameters on the paper-burning threshold are investigated, and the electrical properties of the lines are characterized by using different line thicknesses and sintering laser power densities. In addition, the mechanical and electrical properties of the printed lines and patterns are evaluated by bending and twisting tests. Furthermore, the feasibility of printing silver on different paper types is demonstrated. This research can potentially lead to biodegradable and environmentally friendly printed electronics and sensors.

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