Journal
NANOSCALE
Volume 8, Issue 5, Pages 2937-2943Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nr07941a
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Funding
- EFree, an Energy Frontier Research Center - US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001057]
- National Science Foundation
- National Institutes of Health/National Institutes of General Medical Sciences under NSF [DMR-1332208]
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Mesoporous materials with tailored properties hold great promise for energy harvesting and industrial applications. We have synthesized a novel tungsten bronze mesoporous material (KxWO3; x similar to 0.07) having inverse FDU-12 type pore symmetry and a crystalline framework. In situ small angle X-ray scattering (SAXS) measurements of the mesoporous K0.07WO3 show persistence of a highly ordered meso-scale pore structure to high pressure conditions (similar to 18.5 GPa) and a material with remarkable mechanical strength despite having similar to 35% porosity. Pressure dependent in situ SAXS measurements reveal a bulk modulus. = 44 +/- 4 GPa for the mesoporous KxWO3 which is comparable to the corresponding value for the bulk monoclinic WO3 (gamma-WO3). Evidence from middle angle (MAXS) and wide angle X-ray scattering (WAXS), high-resolution transmission electron microscopy (HR-TEM) and Raman spectroscopy shows that the presence of potassium leads to the formation of a K-bearing orthorhombic tungsten bronze (OTB) phase within a monoclinic WO3 host structure. Our ab initio molecular dynamics calculations show that the formation of the OTB phase provides superior strength to the mesoporous K0.07WO3.
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