Journal
CHEMICAL ENGINEERING SCIENCE
Volume 122, Issue -, Pages 232-239Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2014.09.033
Keywords
Regenerable sorbent; Hg capture; Au nanoparticles; Oxycombustion
Categories
Funding
- Spanish Ministry of Science and Innovation
- European Regional Developments Funds [ENE2011-23412, JAE-Pre_077]
- CSIC
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The present study evaluates an Au/C sorbent based on the direct reduction of a gold salt on a carbon coated structured cordierite monolith for mercury capture under oxyfiring conditions. Both mercury retention efficiency and mercury retention capacity were tested in a bench scale plant under different conditions. The influence of gas temperature (50-150 degrees C) and gas composition (CO2, N-2, SO2, and O-2) on sorbent performance for mercury capture is evaluated and discussed. The amount of mercury captured did not vary significantly with temperature under a CO2 atmosphere. These results were compared with those obtained under N-2 atmosphere with no remarkable differences found between them. High retention efficiencies were obtained despite the small amount of gold used. The presence of SO2 and O-2 in the flue gas led to mercury oxidation that seemed to be mainly promoted by SO2 under the presence of the Au-sorbent. (C) 2014 Elsevier Ltd. All rights reserved.
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