Clusteroluminescence of Unconjugated Polymers: A Review

The current state of research on non-conventional luminescence of unconjugated polymers, which is caused by the occurrence of through-space conjugation due to the overlapping of electronic orbitals of atoms in aggregates formed at high concentrations of substances in solutions or the solid state, is considered. The luminescent properties of different types of polymers containing oxygen, nitrogen, sulfur, silicon, boron, phosphorus is analyzed. The possibilities of the practical applications of polymer cluster luminophores in the fields such as ecosystem monitoring, medicine, biology, encryption, forensics, and optoelectronics are shown.

Automated summary

This study focuses on the non-conventional luminescence of unconjugated polymers, which is caused by through-space conjugation resulting from the overlapping of electronic orbitals of atoms in high concentration aggregates in solutions or solid states. The luminescent properties of various polymers containing different atoms, such as oxygen, nitrogen, sulfur, silicon, boron, and phosphorus, are analyzed. The practical applications of polymer cluster luminophores in fields like ecosystem monitoring, medicine, biology, encryption, forensics, and optoelectronics are demonstrated.