Journal
CHEMICAL ENGINEERING JOURNAL
Volume 263, Issue -, Pages 127-134Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2014.10.105
Keywords
Depth filtration; Permeability loss; Volumetric expansion; Water treatment; Zero-valent iron
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The use of granular metallic iron (Fe-0) as filter material is gaining acceptance in the field of water treatment. Few works have been directed at developing design guidance for efficient Fe-0 filters. This note consolidates earlier works and provides the scientific basis for the design and evaluation of Fe-0 filters for water treatment at any scale. The approach assumes uniform corrosion of individual Fe-0 particles and utilizes the radius loss (X = R-0 - R) to asses the extent of porosity loss in the whole system. Results corroborate that, for R-0 <= 1.0 mm, sustainable filters must content less than 53% Fe-0 (v/v). A universal equation of Fe-0 filters is provided given X as a function of the initial radius R-0, the initial volume of Fe-0, the initial porosity of the filter and the coefficient of volumetric expansion (O-2 availability). This equation should be routinely incorporated in simulations for modeling the hydraulic conductivity of Fe-0 filters. The model improves the discussion of published data on porosity loss. (C) 2014 Elsevier B.V. All rights reserved.
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