Ni(ii)-catalyzed dehydrative alkynylation of unactivated (hetero)aryl C–H bonds using oxygen: a user-friendly approach

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ni(ii)/BINOL-catalyzed alkenylation of unactivated C(sp3)–H bonds

(2015) Yue-Jin Liu et al.   CHEMICAL COMMUNICATIONS

Nickel-catalyzed thiolation of unactivated aryl C–H bonds: efficient access to diverse aryl sulfides

(2015) Sheng-Yi Yan et al.   CHEMICAL COMMUNICATIONS

Nickel-catalyzed directed sulfenylation of sp2 and sp3 C–H bonds

(2015) Xiaohan Ye et al.   CHEMICAL COMMUNICATIONS

Nickel-catalyzed direct thiolation of unactivated C(sp3)–H bonds with disulfides

(2015) Sheng-Yi Yan et al.   CHEMICAL COMMUNICATIONS

A sustainable and simple catalytic system for direct alkynylation of C(sp2)–H bonds with low nickel loadings

(2015) Yue-Jin Liu et al.   CHEMICAL COMMUNICATIONS

Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions

(2015) Luis C. Misal Castro et al.   CHEMISTRY LETTERS

Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis

(2015) Cong Lin et al.   ORGANIC LETTERS

Nickel-Catalyzed Direct Thiolation of C(sp3)–H Bonds in Aliphatic Amides

(2015) Xie Wang et al.   ORGANIC LETTERS

Reusable directing groups [8-aminoquinoline, picolinamide, sulfoximine] in C(sp3)–H bond activation: present and future

(2015) Raja K. Rit et al.   TETRAHEDRON

Transition-Metal-Catalyzed Arylation of Unactivated C(sp3)—H Bonds Assisted by Bidentate Directing Groups

(2015) Bo Zhang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed CH Alkynylation of Arenes at Room Temperature

(2014) Chao Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

(2014) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Copper/Silver-Mediated Directortho-Ethynylation of Unactivated (Hetero)aryl CH Bonds with Terminal Alkyne

(2014) Yue-Jin Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Site-Selective Alkylation of Unactivated C(sp3)–H Bonds

(2014) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Mediated Ortho C–H Alkynylation of (Hetero)Arenes with Terminal Alkynes

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

(2014) Fang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni(II)-Catalyzed Oxidative Coupling between C(sp2)–H in Benzamides and C(sp3)–H in Toluene Derivatives

(2014) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Direct Alkynylation of Arenes with Copper Acetylides

(2014) Cédric Theunissen et al.   ORGANIC LETTERS

Copper-Mediated Tandem Oxidative C(sp2)–H/C(sp)–H Alkynylation and Annulation of Arenes with Terminal Alkynes

(2014) Jiaxing Dong et al.   ORGANIC LETTERS

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

Stereoselective Synthesis of Chiral α-Amino-β-Lactams through Palladium(II)-Catalyzed Sequential Monoarylation/Amidation of C(sp3)H Bonds

(2013) Qi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Pyrroles by Click Reaction: Silver-Catalyzed Cycloaddition of Terminal Alkynes with Isocyanides

(2013) Meng Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Cross-Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading

(2013) Xiaoming Jie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cover Picture: Recoding the Genetic Code with Selenocysteine (Angew. Chem. Int. Ed. 1/2014)

(2013) Markus J. Bröcker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative cross-coupling/cyclization to build polysubstituted pyrroles from terminal alkynes and β-enamino esters

(2013) Jie Ke et al.   CHEMICAL COMMUNICATIONS

Chemicals from Alkynes with Palladium Catalysts

(2013) Rafael Chinchilla et al.   CHEMICAL REVIEWS

Palladium(0)-Catalyzed Alkynylation of C(sp3)–H Bonds

(2013) Jian He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Alkylation of C–H Bonds in Benzamides and Acrylamides with Functionalized Alkyl Halides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(ii)-catalyzed alkoxylation of unactivated C(sp3)–H and C(sp2)–H bonds using a removable directing group: efficient synthesis of alkyl ethers

(2013) Fa-Jie Chen et al.   Chemical Science

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

(2012) Alison N. Campbell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen

(2012) Wanqing Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-catalyzed direct oxidative annulation of N-iminopyridinium ylides with terminal alkynes using O2as oxidant

(2012) Shengtao Ding et al.   CHEMICAL COMMUNICATIONS

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

(2012) Zhuangzhi Shi et al.   CHEMICAL SOCIETY REVIEWS

Electrophilic alkynylation: the dark side of acetylene chemistry

(2012) Jonathan P. Brand et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed C–H Bond Direct Alkynylation of 5-Membered Heteroarenes: A Well-Defined Synthetic Route to Azole Derivatives Containing Two Different Alkynyl Groups

(2012) Fumitoshi Shibahara et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans

(2012) Chuan He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Para-Selective Gold-Catalyzed Direct Alkynylation of Anilines

(2012) Jonathan P. Brand et al.   ORGANIC LETTERS

C2-Selective Direct Alkynylation of Indoles

(2012) Gergely L. Tolnai et al.   ORGANIC LETTERS

Mechanistic aspects of oxidation of palladium with O2

(2012) LiQun Jin et al.   Science China-Chemistry

Palladium-catalyzed oxidative alkynylation of arene C–H bond using the chelation-assisted strategy

(2012) Seok Hwan Kim et al.   TETRAHEDRON

Asymmetric catalytic carbon–carbon coupling reactions via C–H bond activation

(2012) Lei Yang et al.   Catalysis Science & Technology

A Palladium-Catalyzed Aminoalkynylation Strategy towards Bicyclic Heterocycles: Synthesis of (±)-Trachelanthamidine

(2011) Stefano Nicolai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Synthesis of Heterocycles via Electrophilic Cyclization of Alkynes Containing Heteroatom

(2011) Benhur Godoi et al.   CHEMICAL REVIEWS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Nickel-Catalyzed Chelation-Assisted Transformations Involving Ortho C–H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes

(2011) Hirotaka Shiota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Alkynylation of Heterocycles with Terminal Alkynes under Air Conditions

(2011) Seok Hwan Kim et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct ortho-Alkynylation of Aromatic Carboxylic Acid Derivatives

(2011) Yusuke Ano et al.   ORGANIC LETTERS

Metal-Mediated Oxidative Cross-Coupling of Terminal Alkynes: A Promising Strategy for Alkyne Synthesis

(2010) Zhihui Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal Inverse Sonogashira Reaction: Direct Alkynylation of Arenes and Heterocycles with Alkynyl Halides

(2010) Alexander S. Dudnik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed direct oxidative Heck–Cassar–Sonogashira type alkynylation of indoles with alkynes under oxygen

(2010) Luo Yang et al.   CHEMICAL COMMUNICATIONS

Copper-Mediated Direct Cross-Coupling of 1,3,4-Oxadiazoles and Oxazoles with Terminal Alkynes

(2010) Masanori Kitahara et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room Temperature Direct Alkynylation of 1,3,4-Oxadiazoles with Alkynyl Bromides under Copper Catalysis

(2010) Tsuyoshi Kawano et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Aerobic Oxidative Cross-Coupling Reactions of Terminal Alkynes with Alkylzinc Reagents

(2010) Mao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Ethynylation of Arenes

(2010) Teresa de Haro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2as an Oxidant

(2010) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel- and Copper-Catalyzed Direct Alkynylation of Azoles and Polyfluoroarenes with Terminal Alkynes under O2or Atmospheric Conditions

(2010) Naoto Matsuyama et al.   ORGANIC LETTERS

Direct Alkynylation of Indole and Pyrrole Heterocycles

(2009) Jonathan P. Brand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides

(2009) Naoto Matsuyama et al.   ORGANIC LETTERS

Nickel-Catalyzed Oxidative Coupling Reactions of Two Different Terminal Alkynes Using O2as the Oxidant at Room Temperature: Facile Syntheses of Unsymmetric 1,3-Diynes

(2009) Weiyan Yin et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes

(2009) Mamoru Tobisu et al.   ORGANIC LETTERS

Pd-Catalyzed Intramolecular Oxyalkynylation of Alkenes with Hypervalent Iodine

(2009) Stefano Nicolai et al.   ORGANIC LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS