4.7 Article

High-yield production of highly conductive graphene via reversible covalent chemistry

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 14, Pages 2806-2809

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09144b

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Funding

  1. National Basic Research Program of China (973 Program) [2012CB933402, 2013CB933001]
  2. Natural Science Foundation of China [51161120361, 51433005]
  3. Research Grant of Incheon National University

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On the basis of the Diels-Alder reaction of graphite and tetracyanoethylene, graphite has been mechanically exfoliated into graphene adducts in a yield up to 38%. The graphene adduct can restore its conjugated structure via retro-Diels-Alder reaction under mild conditions, exhibiting a high conductivity of 1035 S m(-1).

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