Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5283-5286Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08068h
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Funding
- University of Washington
- University of Washington Innovation Award
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The synthesis and characterization of crystalline colloidal zinc phosphide quantum dots with observable excitonic transitions ranging between 424-535 nm(2.3-2.9 eV) are reported. A ternary combination of ZnEt2, Zn(O2CR)(2), and P(SiMe3)(3), forms a pentanuclear zinc cluster on mixing followed by conversion to (Et2Zn)P(ZnO2CR)(2)(SiMe3) in a rate-determining step prior to quantum dot formation.
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