Tuning Reactivity of Zr-Substituted Keggin Phosphotungstate in Alkene Epoxidation through Balancing H2O2 Activation Pathways: Unusual Effect of Base

Exploring the Reactivity of Polyoxometalates toward Proteins: From Interactions to Mechanistic Insights

(2023) David E. Salazar Marcano et al.   JACS Au

Resolving the Mechanism for H2O2 Decomposition over Zr(IV)-Substituted Lindqvist Tungstate: Evidence of Singlet Oxygen Intermediacy

(2023) Nataliya V. Maksimchuk et al.   ACS Catalysis

The Control of the Coordination Chemistry for the Genesis of Heterogeneous Catalytically Active Sites in Oxidation Reactions

(2022) Chiara Bisio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkene Epoxidation and Thioether Oxidation with Hydrogen Peroxide Catalyzed by Mesoporous Zirconium-Silicates

(2022) Irina D. Ivanchikova et al.   Catalysts

Concepts of Heterogeneously Catalyzed Liquid‐Phase Oxidation of Cyclohexene with tert ‐Butyl Hydroperoxide, Hydrogen Peroxide and Molecular Oxygen

(2022) Julia Büker et al.   ChemCatChem

Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

(2022) Zhihui Ni et al.   MOLECULES

The Dawn of Metal-Oxo Clusters as Artificial Proteases: From Discovery to the Present and Beyond

(2021) Francisco de Azambuja et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic performance of Zr‐based metal‐organic frameworks Zr‐abtc and MIP‐200 in selective oxidations with H2O2

(2021) Nataliya Maksimchuk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

(2021) Oxana Kholdeeva et al.   Catalysts

Activation of H2O2 over Zr(IV). Insights from Model Studies on Zr-Monosubstituted Lindqvist Tungstates

(2021) Nataliya V. Maksimchuk et al.   ACS Catalysis

Catalyst Design for Alkene Epoxidation by Molecular Analogues of Heterogeneous Titanium-Silicalite Catalysts

(2020) Albert Solé-Daura et al.   ACS Catalysis

Reaction Pathway Discrimination in Alkene Oxidation Reactions by Designed Ti‐Siloxy‐Polyoxometalates

(2020) Teng Zhang et al.   ChemCatChem

Why does Nb(V) show higher heterolytic pathway selectivity than Ti(IV) in epoxidation with H2O2? Answers from model studies on Nb- and Ti-substituted Lindqvist tungstates

(2019) Nataliya V. Maksimchuk et al.   ACS Catalysis

Protons Make Possible Heterolytic Activation of Hydrogen Peroxide over Zr-Based Metal–Organic Frameworks

(2019) Nataliya V. Maksimchuk et al.   ACS Catalysis

Unveiling the Active Surface Sites in Heterogeneous Titanium-Based Silicalite Epoxidation Catalysts: Input of Silanol-Functionalized Polyoxotungstates as Soluble Analogues

(2018) Teng Zhang et al.   ACS Catalysis

Buffer-Induced Acceleration and Inhibition in Polyoxometalate-Catalyzed Organophosphorus Ester Hydrolysis

(2018) Daniel L. Collins-Wildman et al.   ACS Catalysis

Relevance of Protons in Heterolytic Activation of H2O2 over Nb(V): Insights from Model Studies on Nb-Substituted Polyoxometalates

(2018) Nataliya V. Maksimchuk et al.   ACS Catalysis

Toward understanding the unusual reactivity of mesoporous niobium silicates in epoxidation of C C bonds with hydrogen peroxide

(2017) Irina D. Ivanchikova et al.   JOURNAL OF CATALYSIS

Superoxide Ion: Generation and Chemical Implications

(2016) Maan Hayyan et al.   CHEMICAL REVIEWS

Alkene Epoxidation Catalyzed by Ti-Containing Polyoxometalates: Unprecedented β-Oxygen Transfer Mechanism

(2016) Pablo Jiménez-Lozano et al.   INORGANIC CHEMISTRY

Recent Advances in Polyoxometalate-Catalyzed Reactions

(2015) Sa-Sa Wang et al.   CHEMICAL REVIEWS

Multinuclear Diffusion NMR Spectroscopy and DFT Modeling: A Powerful Combination for Unraveling the Mechanism of Phosphoester Bond Hydrolysis Catalyzed by Metal-Substituted Polyoxometalates

(2015) Thi Kim Nga Luong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrolysis of the RNA model substrate catalyzed by a binuclear ZrIV-substituted Keggin polyoxometalate

(2015) Thi Kim Nga Luong et al.   DALTON TRANSACTIONS

Oxidovanadium(V) Anchored to Silanol-Functionalized Polyoxotungstates: Molecular Models for Single-Site Silica-Supported Vanadium Catalysts

(2015) Geoffroy Guillemot et al.   ACS Catalysis

Comparative study of titanium-functionalized UiO-66: support effect on the oxidation of cyclohexene using hydrogen peroxide

(2015) Huong Giang T. Nguyen et al.   Catalysis Science & Technology

Hydrolytic Stability and Hydrogen Peroxide Activation of Zirconium-Based Oxoclusters

(2014) Francesco Faccioli et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Solution Speciation of the Dinuclear ZrIV-Substituted Keggin Polyoxometalate [{α-PW11O39Zr(μ-OH)(H2O)}2]8-and Its Reactivity towards DNA-Model Phosphodiester Hydrolysis

(2014) Thi Kim Nga Luong et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Zirconium(IV)- and hafnium(IV)-containing polyoxometalates as oxidation precatalysts: Homogeneous catalytic epoxidation of cyclooctene by hydrogen peroxide

(2014) Hiroki Aoto et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways

(2014) Heather M. Neu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent developments in liquid-phase selective oxidation using environmentally benign oxidants and mesoporous metal silicates

(2014) Oxana A. Kholdeeva   Catalysis Science & Technology

Catalytic Oxidation of Light Alkanes (C1–C4) by Heteropoly Compounds

(2013) Miao Sun et al.   CHEMICAL REVIEWS

Amide bond hydrolysis in peptides and cyclic peptides catalyzed by a dimeric Zr(iv)-substituted Keggin type polyoxometalate

(2013) Hong Giang T. Ly et al.   DALTON TRANSACTIONS

Hydrogen Peroxide Activation over TiIV: What Have We Learned from Studies on Ti-Containing Polyoxometalates?

(2013) Oxana A. Kholdeeva   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

(2012) Pablo Jiménez-Lozano et al.   CHEMICAL COMMUNICATIONS

Structure, properties and reactivity of polyoxometalates: a theoretical perspective

(2012) Xavier López et al.   CHEMICAL SOCIETY REVIEWS

Rational design of single-site heterogeneous catalysts: towards high chemo-, regio- and stereoselectivity

(2012) V. Dal Santo et al.   PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Reactive ZrIV and HfIV Butterfly Peroxides on Polyoxometalate Surfaces: Bridging the Gap between Homogeneous and Heterogeneous Catalysis

(2011) Mauro Carraro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hexazirconium- and Hexahafnium-Containing Tungstoarsenates(III) and Their Oxidation Catalysis Properties

(2010) Ghada Al-Kadamany et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dendritic Zirconium-Peroxotungstosilicate Hybrids: Synthesis, Characterization, and Use as Recoverable and Reusable Sulfide Oxidation Catalysts

(2010) Claire Jahier et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Epoxidation of Alkenes with H2O2 Catalyzed by Dititanium-Containing 19-Tungstodiarsenate(III): Experimental and Theoretical Studies

(2010) Baira G. Donoeva et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Chemistry of Group IV Metal Ion-Containing Polyoxometalates

(2010) Kenji Nomiya et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Activation of Molecular Oxygen, Polyoxometalates, and Liquid-Phase Catalytic Oxidation

(2010) Ronny Neumann   INORGANIC CHEMISTRY

Synthesis and structure of dinuclear hafnium(IV) and zirconium(IV) complexes sandwiched between 2 mono-lacunary α-Keggin polyoxometalates

(2009) Kenji Nomiya et al.   DALTON TRANSACTIONS

Peroxo-Zr/Hf-Containing Undecatungstosilicates and -Germanates

(2009) Sib Sankar Mal et al.   INORGANIC CHEMISTRY

E factors, green chemistry and catalysis: an odyssey

(2008) Roger A. Sheldon   CHEMICAL COMMUNICATIONS

Synthesis and Catalysis of Di- and Tetranuclear Metal Sandwich-Type Silicotungstates [(γ-SiW10O36)2M2(μ-OH)2]10−and [(γ-SiW10O36)2M4(μ4-O)(μ-OH)6]8−(M = Zr or Hf)

(2008) Yuji Kikukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY