4.7 Article

Herringbone to cofacial solid state packing via H-bonding in diketopyrrolopyrrole (DPP) based molecular crystals: influence on charge transport

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 1, Pages 97-100

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06063f

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Funding

  1. Ministry of Communication and Information Technology under a grant for the Centre of Excellence in Nanoelectronics, Phase II
  2. Council of Scientific and Industrial Research (CSIR) for senior research fellowship (SRF)

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Themono-alkylation of DPP derivatives leads to cofacial pi-pi stacking via H-bonding unlike their di-alkylated counterparts, which exhibit a classical herringbone packing pattern. Single crystal organic field-effect transistor (OFET) measurements reveal a significant enhancement of charge carrier mobility for mono-hexyl DPP derivatives.

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