Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5290-5293Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08662g
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Funding
- North Carolina American Chemical Society (NC-ACS)
- UNC-CH E. C. Markham Undergraduate Research Fellowship
- Department of Energy Office of Science Graduate Fellowship Program (DOE SCGF)
- ORISE-ORAU [DE-AC05-06OR23100]
- UNC EFRC: Center for Solar Fuels Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001011]
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A Ni(II) complex degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen. Comparison with a similar compound permitted investigation of the degradation mechanism.
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