4.2 Article

Dimethyl sulfoxide as a green solvent for successful precipitative polyheterocyclization based on nucleophilic aromatic substitution, resulting in high molecular weight PIM-1

Journal

MENDELEEV COMMUNICATIONS
Volume 26, Issue 4, Pages 362-364

Publisher

ELSEVIER
DOI: 10.1016/j.mencom.2016.07.033

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Funding

  1. Russian Academy of Sciences
  2. Russian Foundation for Basic Research [ofi-m 14-29-04011]

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A new method for the effective synthesis of high molecular weight polymer of intrinsic microporosity (PIM-1) powder widely employed for gas separation membranes was successfully developed using precipitative polyheterocyclization process in non-toxic DMSO.

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