4.7 Article

Core-shell hierarchical WO2/WO3 microspheres as an electrocatalyst support for methanol electrooxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 83, Pages 15297-15299

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06603d

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Funding

  1. National Natural Science Foundation of China [51404110, 21506187]
  2. Jiangxi Natural Science Foundation of China [20151BAB213011]
  3. Postdoctoral Preferred Project Fund of Jiangxi Province [2014zy15]
  4. Jiangxi Ganpo 555 Project for Excellent Talents

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Core-shell WO2/WO3 microspheres were prepared using a phase transformation route. The as-prepared Pt-WO2/WO3 catalyst exhibits excellent activity and stability towards methanol electrooxidation, compared with those of commercial PtRu/C and Pt/h-WO3, due to the decrease of the electron-transfer resistance by the modification of using WO2 as a conductive oxide.

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