4.7 Article

Large phenyl-substituted acenes by cycloaddition reactions of the 2,6-naphthodiyne synthon

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5418-5420

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00205b

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Funding

  1. European Union (Project PAMS) [610446]
  2. Spanish Ministry of Science and Competitiveness (MINECO) [CTQ2010-18208]
  3. Xunta de Galicia [10PXIB2200222PR]
  4. FEDER
  5. Spanish Ministry of Education

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Phenyl-substituted tetra-, penta-, hexa- and octacenes were easily obtained starting from a readily available naphthalene-based bisaryne precursor. This approach to large acenes involves a sequence of two Diels-Alder cycloadditions with dienones followed by two CO extrusion reactions.

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