4.7 Article

One-pot selective synthesis of a fullerene bisadduct for organic solar cell applications

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 48, Pages 9837-9840

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02701b

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Funding

  1. Australian Renewable Energy Agency within Australian Centre for Advanced Photovoltaics
  2. Australian Research Council Future Fellowship [FT130100500]

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A single isomer of fullerene bisadduct, PC61PF, was obtained from commercially available fullerene derivative, PC61BM, in one pot over two steps. The tether-directed remote functionalization approach provided a very simple and fast method to produce a single isomer of fullerene bisadduct with good yield and easy purification. Bulk heterojunction organic solar cells containing the bisadduct was fabricated and tested.

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