Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 34, Pages 7368-7371Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00850f
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Funding
- 973 Program [2012CB921603]
- 863 Program [2011AA010801]
- Natural Science Foundation of China [11174187, 10934004, 11204166, 11404200]
- Doctoral Foundation of the Education Ministry of China [20121401120016]
- PCSIRT [IRT13076]
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We report that by applying an electric field to a single squaraine-derived rotaxane (SR) molecule on bare glass, the fluorescence can be completely quenched. The molecule undergoes a reversible fluorescence switch between a zero-field on'' state and a high-field off'' state, which is attributed to intramolecular electron transfer within the SR molecule.
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