4.1 Article

Effect of Silver Addition on Cu-based Shape Memory Alloys

Journal

CHEMICAL AND BIOCHEMICAL ENGINEERING QUARTERLY
Volume 37, Issue 3, Pages 153-161

Publisher

CROATIAN SOC CHEMICAL ENGINEERING TECHNOLOGY
DOI: 10.15255/CABEQ.2023.2186

Keywords

shape memory alloys; Cu-Al-Ag alloys; microstructure; phase transformations; martensite

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Shape memory alloys (SMAs) are smart materials with unique properties of super elasticity and shape memory effect. In this study, Cu10Al-1Ag alloy was prepared and its microstructure and transformation temperatures were analyzed, revealing the fully formed martensite structure in the quenched state.
Shape memory alloys (SMAs) are smart materials with unique properties of super elasticity and shape memory effect. These properties are the consequence of thermoelastic martensitic transformation, which can occur under thermal or mechanical deformation. Cu-Al-Ag alloys have high temperatures of martensite transformation, unlike other SMAs, which makes them suitable for use in specific applications. In this paper, Cu10Al-1Ag alloy was prepared by melting pure metals in an electric arc furnace and casting the melt in a cylindrical mold. The microstructure of the as-cast and quenched material was determined by optical microscopy (OM) and scanning electron microscopy (SEM) equipped with energy dispersive analysis (EDS). X-ray diffraction (XRD) analysis was performed to identify crystal phases in the microstructure, while transformation temperatures were determined by differential scanning calorimetry (DSC). The hardness of Cu-Al-Ag SMA was also determined with a microhardness tester. The results showed partially formed martensite in the as-cast state, and fully formed martensite structure, 18R-type, in the quenched Cu-10Al-1Ag alloy.

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