Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 15, Pages 3106-3108Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09820j
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Funding
- National Basic Research Program of China (973 Program) [2011CB808600]
- National Natural Science Foundation of China [21372162, 21432006]
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Chiral N,N'-dioxide-In(OTf)(3) complexes were developed as efficient catalysts to catalyze the vinylogous Mukaiyama aldol reaction of the silyl dienol ester with aldehydes. The corresponding delta-hydroxy-alpha,beta-unsaturated esters were obtained in up to 99% yield and 98% ee. Moreover, the obtained (R)-3v can be easily transformed to natural bioactive products.
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