Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 19, Pages 4001-4004Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10304a
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Funding
- LMU Munich
- Deutsche Forschungsgemeinschaft [SFB 749]
- Excellence Cluster CIPSM - Center of Integrated Protein Science Munich
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The synthesis of novel, chignolin-derived peptides comprising the azobenzene photoswitch [3-(3-aminomethyl)phenylazo]phenylacetic acid (AMPP) is reported. Reversible photoswitching behavior led to folding into beta-hairpin-like structures, as unequivocally demonstrated by CD, FT-IR and NMR spectroscopy.
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