4.7 Article

Predicting the structure and interfacial activity of diblock brush, mixed brush, and Janus-grafted nanoparticles

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 25, Pages 5440-5443

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08659g

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Funding

  1. National Science Foundation [NSF DMR-1410246]
  2. University Research Foundation (URF) of the University of Pennsylvania

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A modeling framework is developed to describe the structure and properties of fluid interfaces stabilized with grafted nanoparticles. The framework is demonstrated on nanoparticles functionalized with polymers of various grafting architectures; we find that the conformation of the grafted chains plays an important role in the interfacial tension.

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