4.7 Article

Iridium-catalyzed allyl-allyl cross-coupling of allylic carbonates with (E)-1,3-diarylpropenes

Journal

CHEMICAL COMMUNICATIONS
Volume 51, Issue 59, Pages 11834-11836

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04085j

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Funding

  1. National Natural Science Foundation of China [21172143, 21232004, 21172145, 21372152]
  2. Program of Shanghai Subject Chief Scientists [14XD1402300]
  3. Nippon Chemical Industrial Co. Ltd.

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An efficient Ir-catalyzed allyl-allyl cross-coupling reaction of allylic carbonates with (E)-1,3-diarylpropenes was developed to form linear allylated products, 1,5-dienes, regioselectively in excellent yields and with high turnover numbers (up to 2000 S/Ir).

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