Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 56, Pages 11248-11251Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03654b
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Funding
- Australian Research Council Linkage project [LP120100435]
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For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations. This relationship can be further employed towards aiding structural solutions and predicting physical properties of novel complex transition metal hydrides.
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