Recent Advances in First-Row Transition Metal-Catalyzed Reductive Coupling Reactions for π-Bond Functionalization and C-Glycosylation

Diversification of Glycosyl Compounds via Glycosyl Radicals

(2023) Yi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective C‐Aryl Glycosylation by Catalytic Cross‐Coupling of Heteroaryl Glycosyl Sulfones

(2023) Quanquan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Pathway Glycosylation Empowered by Bench-Stable Glycosyl Donors

(2023) Weidong Shang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Multicomponent Synthesis of C ‐Acyl Glycosides by Consecutive Cross‐Electrophile Couplings

(2022) Yi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Photoinduced, Nickel‐Catalyzed Reaction for the Stereoselective Assembly of C‐ Linked Glycosides and Glycopeptides

(2022) Yi Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed site- and stereoselective reductive alkylalkynylation of alkynes

(2021) Yi Jiang et al.   Chem

Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group

(2021) Yi-Zhou Zhan et al.   Nature Communications

Photoinduced Nickel-Catalyzed Deaminative Cross-Electrophile Coupling for C(sp2)–C(sp3) and C(sp3)–C(sp3) Bond Formation

(2021) Tao Yang et al.   ACS Catalysis

Synthesis of C-glycosides by Ti-catalyzed stereoselective glycosyl radical functionalization

(2021) Yi Jiang et al.   Chem

Site-Selective 1,2-Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

(2020) Shang-Zheng Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Reductive Vinylation of Tertiary Alkyl Oxalates with Activated Vinyl Halides

(2020) Yang Ye et al.   ORGANIC LETTERS

Recent Advances in Nickel-Catalyzed Three-Component Difunctionalization of Unactivated Alkenes

(2020) Hai-Yong Tu et al.   SYNTHESIS-STUTTGART

Broadly Applicable Directed Catalytic Reductive Difunctionalization of Alkenyl Carbonyl Compounds

(2020) Tao Yang et al.   Chem

Mechanisms of Nickel-Catalyzed Coupling Reactions and Applications in Alkene Functionalization

(2020) Justin Diccianni et al.   ACCOUNTS OF CHEMICAL RESEARCH

On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides

(2020) Mingbin Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Three-Component Fluoroalkylarylation of Unactivated Olefins through Nickel-Catalyzed Cross-Electrophile Coupling

(2020) Hai-Yong Tu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel‐Catalyzed Dicarbofunctionalization of Alkenes †

(2020) Yun‐Cheng Luo et al.   CHINESE JOURNAL OF CHEMISTRY

Chemoselective Union of Olefins, Organohalides, and Redox-Active Esters Enables Regioselective Alkene Dialkylation

(2020) Tao Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkyl halides as both hydride and alkyl sources in catalytic regioselective reductive olefin hydroalkylation

(2020) Xianxiao Chen et al.   Nature Communications

Ni-Catalyzed Asymmetric Reductive Arylalkylation of Unactivated Alkenes

(2019) Youxiang Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Asymmetric Reductive Diarylation of Vinylarenes

(2019) David Anthony et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes

(2019) Zhi-Xiong Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Driven Organic Photochemical Reactions in the Absence of External Photocatalysts

(2019) Yi Wei et al.   SYNTHESIS-STUTTGART

Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights

(2019) Wei Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Survival Guide for the “Electro-curious”

(2019) Cian Kingston et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Reversed C -Acyl Glycosides through Ni/Photoredox Dual Catalysis

(2018) Shorouk O. Badir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent progress of C-glycosylation methods in the total synthesis of natural products and pharmaceuticals

(2018) Hongze Liao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ni(i)–Ni(iii) vs. Ni(ii)–Ni(iv): mechanistic study of Ni-catalyzed alkylation of benzamides with alkyl halides

(2018) Yingzi Li et al.   Organic Chemistry Frontiers

Ni-Catalyzed Regioselective Alkylarylation of Vinylarenes via C(sp3)–C(sp3)/C(sp3)–C(sp2) Bond Formation and Mechanistic Studies

(2018) Shekhar KC et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Reductive Diarylation of Activated Alkenes by Domino Cyclization/Cross-Coupling

(2018) Kuai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay

(2018) Xian Zhao et al.   Nature Communications

Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors

(2018) Xiangyu Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

Acyl Glycosides through Stereospecific Glycosyl Cross-Coupling: Rapid Access to C(sp3)-Linked Glycomimetics

(2018) Feng Zhu et al.   ACS Central Science

Synthesis of Aryl C-Glycosides via Iron-Catalyzed Cross Coupling of Halosugars: Stereoselective Anomeric Arylation of Glycosyl Radicals

(2017) Laksmikanta Adak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes

(2017) Andrés García-Domínguez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Stereoselective Dicarbofunctionalization of Alkynes

(2016) Zhaodong Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Antivirulence C-Mannosides as Antibiotic-Sparing, Oral Therapeutics for Urinary Tract Infections

(2016) Laurel Mydock-McGrane et al.   JOURNAL OF MEDICINAL CHEMISTRY

Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates

(2016) Xueqiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical Ni-Catalyzed Aryl–Alkyl Cross-Coupling of Secondary Redox-Active Esters

(2016) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides

(2016) Kierra M. M. Huihui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies

(2016) Xiangcheng Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents

(2016) T. Qin et al.   SCIENCE

Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation

(2016) Xi Lu et al.   Nature Communications

Organic Synthesis Enabled by Light-Irradiation of EDA Complexes: Theoretical Background and Synthetic Applications

(2016) Carolina G. S. Lima et al.   ACS Catalysis

How Low Does Iron Go? Chasing the Active Species in Fe-Catalyzed Cross-Coupling Reactions

(2015) Robin B. Bedford   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations

(2015) Jun Gu et al.   Organic Chemistry Frontiers

Cross-Electrophile Coupling: Principles of Reactivity and Selectivity

(2014) Daniel A. Everson et al.   JOURNAL OF ORGANIC CHEMISTRY

Ni-Catalyzed Reductive Coupling of Alkyl Acids with Unactivated Tertiary Alkyl and Glycosyl Halides

(2014) Chenglong Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Flexible Synthesis of 2-Deoxy-C-Glycosides and (1→2)-, (1→3)-, and (1→4)-LinkedC-Glycosides

(2013) Dennis C. Koester et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Mediated Inter- and Intramolecular Reductive Cross-Coupling of Unactivated Alkyl Bromides and Aryl Iodides at Room Temperature

(2012) Chang-Song Yan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Transition-Metal-Free Homocoupling of 1-Haloalkynes: A Facile Synthesis of Symmetrical 1,3-Diynes

(2010) Zhengwang Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereoselective Ni-Catalyzed Negishi Cross-Coupling Approach to Saturated, Fully OxygenatedC-Alkyl andC-Aryl Glycosides

(2008) Hegui Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

(2008) Katrina H. Jensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY