Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 30, Pages 6633-6636Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01151e
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Funding
- National Natural Science Foundation of China [21125210, 21421091]
- Chinese Academy of Science
- Major State Basic Research Development Program [2011CB808700]
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An efficient Pd-catalyzed cross-coupling/cycloisomerization of 3-(2-pyridyl) propargyl carbonates with organoboronic acids has been developed, which provides a straightforward route for the synthesis of 1,3-disubstituted indolizines with a wide variety of substituents. The mechanistic study indicates that the reaction proceeds via formation of an allenyl pyridine intermediate through palladium-catalyzed coupling reaction followed by cyclization.
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