Solvent mixture effect in the zinc hexacyanoferrate (III) nanoparticles: Synthesis, characterization and voltammetric application

This work describes the preparation and characterization of size-controlled zinc hexacyanoferrate (III) nanoparticles (ZnH). They were prepared using different proportions of water/formamide in the complexation reaction of Zn2+ with [Fe-III(CN)(6)](3)(-). The materials were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), Ultraviolet-Visible Spectroscopy (UV-vis), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX) and Cyclic Voltammetry (CV). The cyclic voltammograms of the modified graphite paste electrode with ZnH-1, ZnH-2, ZnH-3 and ZnH-4 showed a well-defined redox couple with formal potential (E-theta')= 0.94 +/- 0.01 V (v=20 mV s(-1); KCl 1.0 M)) attributed to the redox process [Fe-II(CN)(6)]/[Fe-III(CN)(6)] in the presence of Zn2+. The dependence of particle size on the detection of sulfite was verified. (C) 2016 Elsevier Ltd. All rights reserved.