Journal
MACROMOLECULES
Volume 49, Issue 4, Pages 1191-1200Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.6b00137
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Funding
- National Institutes of Health [NIH: 5UO1DE023774]
- National Science Foundation [NSF: CHE1214109]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1214109] Funding Source: National Science Foundation
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Bulk photopolymerization of a library of synthesized multifunctional azides and alkynes was carried out toward developing structure property relationships for CuAAC-based polymer networks. Multifunctional azides and alkynes were formulated with a copper catalyst and a photoinitiator, cured, and analyzed for their mechanical properties. Material properties such as the glass transition temperatures (T-g) show a strong dependence on monomer structure with T-g values ranging from 41 to 90 degrees C for the series of CuAAC monomers synthesized in this study. Compared to the triazoles, analogous thioether-based polymer networks exhibit a 45-49 degrees C lower T-g whereas analogous monomers composed of ethers in place of carbamates exhibit a 40 degrees C lower T-g. Here, the formation of the triazole moiety during the polymerization represents a critical component in dictating the material properties of the ultimate polymer network where material properties such as the rubbery modulus, cross-link density, and T-g all exhibit strong dependence on polymerization conversion, monomer composition, and structure postgelation.
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