Journal
MACROMOLECULES
Volume 49, Issue 6, Pages 2054-2062Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.5b02533
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Funding
- NanoNextNL, a micro and nanotechnology consortium of the Government of The Netherlands [10C]
- Netherlands Organization for Scientific Research (NWO VENI) [722.011.006]
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The use of microreactor technology for the ring-opening polymerization of L-lactide catalyzed by 1,5,7-triazabicyclo[4.4.0]dec-5-ene allows for rapid optimization of reaction parameters (reaction temperature and residence time). At moderate catalyst loading, good control over the polymerization is demonstrated by high conversion of monomer (>95%) and low polydispersity (<1.3) at residence times as low as 2 s. This metal-free, organocatalytic route yields well-defined poly(lactic acid) in continuous flow and by using bicyclononyne- and tetrazine-containing initiators gives access to poly(lactic acid) amenable to click chemistry.
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