4.6 Article

A sustainably produced hydrochar from pomegranate peels for the purification of textile contaminants in an aqueous medium

Journal

SUSTAINABLE CHEMISTRY AND PHARMACY
Volume 31, Issue -, Pages -

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ELSEVIER
DOI: 10.1016/j.scp.2022.100924

Keywords

Hydrochar; Pomegranate peels; Adsorption; Basic red 46 dye

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Hydrothermal Carbonization is an easy, inexpensive, and eco-friendly method to convert waste into sustainable materials. This study used this method to make hydrochar from pomegranate peels and found that it performed well in removing a cationic dye from water. The prepared hydrochar showed good reusability and could be an effective adsorbent for treating colored wastewater.
Hydrothermal Carbonization presents an easy, inexpensive, and eco-friendly method to convert waste from natural resources into sustainable materials. This study used the Hydrothermal Car-bonization (HTC) approach to make hydrochar from locally available pomegranate peels. Several analytical tools were employed for its characterization, including elemental analysis, X-ray Dif-fraction, micro-Raman, Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, Textual analysis, pHpzc, and Boehm titration. The produced hydrochar performed well in remov-ing cationic dye Basic Red 46 (BR46) from an aqueous medium, adsorbing 286.90 and 367.72 mg g-1 within only 5 and 60 min, respectively, at ideal circumstances. The Freundlich model was the most appropriate for the equilibrium data, whilst the pseudo-second-order model was found closest to the kinetic data (R2 = 0.980; Delta qe = 7.934%). Per the thermodynamic study, the dye adsorption was spontaneous (Delta G degrees < 0) and endothermic (Delta H degrees = 32.777 kJ mol-1). Furthermore, the prepared hydrochar (HCPP) has revealed good reusability, as it can be reused up to five times without losing its effectiveness. In summary, the outcomes obtained revealed that HCPP could be an effective and eco-friendly adsorbent for the treatment of colored wastewater.

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