Journal
CHEMCATCHEM
Volume 7, Issue 7, Pages 1177-1183Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201402909
Keywords
alkanes; alkenes; deoxygenation; ketones; oxo-rhenium complexes
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Funding
- Fundacao para a Ciencia e Tecnologia (FCT) [PTDC/QUI-QUI/110080/2009]
- FCT [SFRH/BD/90659/2012]
- [UID/QUI/00100/2013]
- Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/110080/2009, SFRH/BD/90659/2012] Funding Source: FCT
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The first methodology for the direct reductive deoxygenation of ketones catalyzed by high-valent oxo-rhenium complexes by using a silane as reducing agent is described. The systems PhSiH3/[ReOCl3(SMe2)(OPPh3)] (2mmol/5mol%) and PhSiH3/[ReOCl3(PPh3)(2)] (2mmol/5mol%) proved to be efficient for the deoxygenation of aryl ketones, producing selectively the corresponding alkane, or a mixture of alkane and alkene derivatives with the alkane as the major product.
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