4.5 Article

SOME ELECTRIC, THERMAL, AND THERMOELECTRIC PROPERTIES OF SUSPENDED MONOLAYER GRAPHENE

Journal

SIAM JOURNAL ON APPLIED MATHEMATICS
Volume 83, Issue 2, Pages 770-790

Publisher

SIAM PUBLICATIONS
DOI: 10.1137/22M147548X

Keywords

graphene; electron-phonon transport; macroscopic models; equilibrium; conductivity; thermopower

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In this paper, the electric, thermal, and thermoelectric properties of suspended monolayer graphene are investigated through numerical experiments. The heating process and equilibrium state of the suspended graphene sheet under a constant homogeneous electric field are analyzed. The influence of out-of-plane acoustical phonons and electron density on the equilibrium temperature are studied, showing notable effects. The formulas for electronic thermal and electric conductivity and thermopower are derived based on linear irreversible thermodynamics.
In this paper we investigate some electric, thermal, and thermoelectric properties of suspended monolayer graphene. By means of a numerical experiment, which was made employing a previously developed macroscopic model for charge and energy transport in graphene, we analyze how fast a suspended graphene sheet heats up when it is subject to a constant homogeneous electric field and how it reaches the equilibrium state once the electric field is turned off. We consider electrons and all phonon branches and show that the influence of the out-of-plane acoustical phonons on the final equilibrium temperature is notable due to their great surface heat capacity. The influence of the electrons on the equilibrium temperature depends on their density; in fact the higher it is, the more energy they gain from the electric field. The behavior of the system can be theoretically justified on the basis of two important physical properties: the conservation of the total energy and the increase of the total entropy of the electron-phonon system; of the latter we give an almost explicit expression. After that, we study the electronic thermal and electric conductivity and the thermopower by finding formulas which express them as functions of the electron and phonon temperatures and the electron density by using a suitable recasting of the macroscopic model in the framework of linear irreversible thermodynamics.

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