Spin-polarized spatially indirect excitons in a topological insulator

The exciton, a bound state of an electron and a hole, is a fundamental quasiparticle induced by coherent light-matter interactions in semiconductors. When the electrons and holes are in distinct spatial locations, spatially indirect excitons are formed with a much longer lifetime and a higher condensation temperature. One of the ultimate frontiers in this field is to create long-lived excitonic topological quasiparticles by driving exciton states with topological properties, to simultaneously leverage both topological effects and correlation(1,2). Here we reveal the existence of a transient excitonic topological surface state (TSS) in a topological insulator, Bi2Te3. By using time-, spin- and angle-resolved photoemission spectroscopy, we directly follow the formation of a long-lived exciton state as revealed by an intensity buildup below the bulk-TSS mixing point and an anomalous band renormalization of the continuously connected TSS in the momentum space. Such a state inherits the spin-polarization of the TSS and is spatially indirect along the z axis, as it couples photoinduced surface electrons and bulk holes in the same momentum range, which ultimately leads to an excitonic state of the TSS. These results establish Bi2Te3 as a possible candidate for the excitonic condensation of TSSs(3) and, in general, opens up a new paradigm for exploring the momentum space emergence of other spatially indirect excitons, such as moire and quantum well excitons(4-6), and for the study of non-equilibrium many-body topological physics.

Automated summary

By using time-, spin- and angle-resolved photoemission spectroscopy, we directly observe the formation of a long-lived exciton state in a transient excitonic topological surface state (TSS) in Bi2Te3. This state inherits the spin-polarization of the TSS and is spatially indirect along the z axis, as it couples photoinduced surface electrons and bulk holes in the same momentum range, which ultimately leads to an excitonic state of the TSS. These results establish Bi2Te3 as a possible candidate for the excitonic condensation of TSSs and open up a new paradigm for exploring other spatially indirect excitons and non-equilibrium many-body topological physics.