Article
Chemistry, Multidisciplinary
Federico Bruno, Alice Sciortino, Gianpiero Buscarino, Maria Laura Soriano, Angel Rios, Marco Cannas, Franco Gelardi, Fabrizio Messina, Simonpietro Agnello
Summary: This study investigates carbon dots produced via bottom-up and top-down routes using multiple techniques, comparing their structural and optical properties and interaction with mercury ions. Key structural and optical properties common to all types of carbon dots were identified, along with critical differences in optical response and microscopic mechanisms responsible for fluorescence. The study also suggests likely interaction sites of mercury ions on carbon dots and reveals details on mercury-induced fluorescence quenching for optimizing sensing applications.
Review
Chemistry, Physical
Namra Abid, Muhammad Khan, Sara Shujait, Kainat Chaudhary, Muhammad Ikram, Muhammad Imran, Junaid Haider, Maaz Khan, Qasim Khan, Muhammad Maqbool
Summary: This article discusses the synthesis and growth mechanisms of nanomaterials and their effects on their structure and morphology. The top-down and bottom-up synthesis methods are reviewed, compared, and analyzed, along with their advantages, disadvantages, and suitability for specific applications.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2022)
Review
Materials Science, Multidisciplinary
Adrian Gutierrez-Cruz, Ali Roberto Ruiz-Hernandez, Jose Fernando Vega-Clemente, Daniela Guadalupe Luna-Gazcon, Jessica Campos-Delgado
Summary: As nanotechnology advances, nanomaterials like graphene are gaining attention due to their unique properties and potential. This document reviews the synthesis methods of graphene, graphene oxide, and reduced graphene oxide, focusing on important techniques such as chemical vapor deposition and wet-chemical methods. The current production status and challenges of graphene and graphene oxide are analyzed.
JOURNAL OF MATERIALS SCIENCE
(2022)
Review
Chemistry, Multidisciplinary
Minghui Li, Lin Li, Yixuan Fan, Fei Jiao, Dechao Geng, Wenping Hu
Summary: This article provides an overview of etching techniques for 2D materials and their applications in electronic device manufacturing, growth mechanism research, and grain boundary visualization. It introduces commonly used etching techniques and etching modes, and elucidates the etching mechanism. Additionally, it discusses key issues in the etching process and envisions future developments.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Multidisciplinary Sciences
Yonatan Vanunu, Jared M. Hotaling, Mike E. Le Pelley, Ben R. Newell
Summary: The study shows that initial attention in risky choice is driven by perceptual properties of the stimulus, while subsequent choices are more influenced by goal-driven factors. Options with the highest values and largest font sizes have the greatest impact on choice, while distractors may attract attention but do not affect actual decision-making.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2021)
Article
Multidisciplinary Sciences
Juan Diaz-Colunga, Nanxi Lu, Alicia Sanchez-Gorostiaga, Chang-Yu Chang, Helen S. Cai, Joshua E. Goldford, Mikhail Tikhonov, Alvaro Sanchez
Summary: Microbial communities frequently invade one another as a whole, a phenomenon known as community coalescence. This study provides direct evidence that collective invasions can lead to ecological coselection in microbial communities due to cross-feeding interactions at the community level.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Review
Engineering, Biomedical
V. G. DileepKumar, Mysore Santosh Sridhar, Pornanong Aramwit, Valentina K. Krut'ko, Olga N. Musskaya, Ilya E. Glazov, Narendra Reddy
Summary: Hydroxyapatite (HA or HAp) is a widely used biomaterial in bone tissue engineering with varied properties and synthesis methods. Understanding the correlation between synthesis methods and properties of HAp is essential for generating HAp with desired characteristics for specific applications. Doping HAp with minerals or bioentities has been explored to enhance its suitability for various applications.
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
(2022)
Article
Chemistry, Analytical
Chao Wang, Yu Liang, Baofeng Zhao, Zhen Liang, Lihua Zhang, Yukui Zhang
Summary: This study successfully prepared ethane-bridged hybrid monoliths with well-defined large mesopores, which achieved high peak capacity and separation efficiency in top-down proteomic analysis.
ANALYTICAL CHEMISTRY
(2022)
Article
Automation & Control Systems
T. Burr, S. Croft, A. Favalli, T. Krieger, B. Weaver
Summary: This paper reviews progress and presents new results for uncertainty quantification in nuclear safeguards, focusing on data-driven choices in SD estimation, the use of approximate Bayesian computation, computational calibration, revisions to the GUM, and critique of a Unified Theory of Measurement Errors and Uncertainties.
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS
(2021)
Article
Biochemical Research Methods
Stephanie Biedka, Brigitte F. Schmidt, Nolan M. Frey, Sarah M. Boothman, Jonathan S. Minden, Amber Lucas
Summary: This study presents a new protein sample preparation method, ProMTag, which enables whole proteome capture, cleanup, and release of intact proteins, as well as generation of peptides for downstream analysis. The ProMTag workflow yields high percentages for both intact proteins and proteome digests, making it a versatile and high-quality approach for proteome sample preparation.
JOURNAL OF PROTEOME RESEARCH
(2021)
Article
Biology
Hajo Eicken, Finn Danielsen, Josephine-Mary Sam, Maryann Fidel, Noor Johnson, Michael K. Poulsen, Olivia A. Lee, Katie Spellman, Lisbeth Iversen, Peter Pulsifer, Martin Enghoff
Summary: Effective responses to rapid environmental change rely on observations to inform planning and decision-making. Comparing top-down, large-scale program driven approaches with bottom-up approaches initiated and steered at the community level can yield benefits, especially when connecting to Indigenous and local knowledge.
Article
Chemistry, Multidisciplinary
Gyurim Park, Dong Yeon Jeong, Seung Yeon Yu, Jong Jin Park, Jong H. Kim, Hoichang Yang, Youngmin You
Summary: This research demonstrates an advancement in the engineering of emitters with circularly polarized luminescence (CPL) properties. By utilizing a combined top-down and bottom-up strategy, the photoluminescence quantum yield and the luminescence dissymmetry factor were simultaneously amplified. The integration of chiral anions and the formation of helical assemblies of square-planar Pt(II) complexes played crucial roles in activating the CPL-active metal-metal-to-ligand charge transfer transition.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Environmental Sciences
Andreas Froemelt, Arne Geschke, Thomas Wiedmann
Summary: This article discusses a highly detailed, spatially-resolved modelling framework that quantifies local activities and analyzes system-wide environmental and economic effects of planned interventions. Two case studies were conducted to examine production-based greenhouse gas emissions, consumption-based carbon footprints, and regional differences in Switzerland. The importance of providing regionalized information along economic value chains and the potential benefits and drawbacks of detailed scenarios were highlighted.
ENVIRONMENTAL RESEARCH LETTERS
(2021)
Article
Nanoscience & Nanotechnology
Sicong Liu, Shiguang Shang, Ruidong Lv, Yonggang Wang, Jiang Wang, Wei Ren, Yishan Wang
Summary: Study reports a D-shaped fiber-buried Mo2C saturable absorber fabricated by magnetron-sputtering deposition and sol-gel technique. The SA is applied in erbium-doped fiber lasers, enabling stable generation of high-power mode-locked pulses and bound-state soliton pulses.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Environmental Sciences
Margarita Brandt, Isabel Silva-Romero, David Fernandez-Garnica, Esteban Agudo-Adriani, Colleen B. Bove, John F. Bruno
Summary: This study found that nutrient availability, temperature, and herbivory all have impacts on macroalgal biomass. Excluding herbivores significantly increased macroalgal biomass, regardless of season or nutrient availability. However, the interactive effects of nutrients and herbivores differed between the cool and warm seasons. The results suggest that nutrient availability, rather than temperature, modulates the effects of herbivory.
FRONTIERS IN MARINE SCIENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Ahmed M. El-Khawaga, Ayman A. Farrag, Mohamed A. Elsayed, Gharieb S. El-Sayyad, Ahmed I. El-Batal
Summary: In this study, magnesium ferrite nanoparticles functionalized with citric acid (CA) showed excellent antimicrobial potential and removal activity of azo dye, achieving a high removal efficiency of 85% for methyl orange at pH 5.0. The CA-MgFe2O4 NPs exhibited strong antimicrobial activities against S. aureus, E. coli, and C. albicans, with zone of inhibition values of 20.0, 16.0, and 14.0 mm, respectively.
JOURNAL OF CLUSTER SCIENCE
(2022)
Article
Polymer Science
Ahmed I. A. Abd El-Mageed, Amro K. F. Dyab, Lamiaa A. Mohamed, Fouad Taha, Hisham A. Essawy
Summary: Polystyrene microspheres were prepared in magnetized form using a modified route of suspension polymerization with a surface-active agent as stabilizer, ensuring uniform size and stable magnetic property. The addition of oleophilized iron oxide nanoparticles in the monomer phase played a key role in achieving the successful production of microspheres with excellent and stable ferromagnetism.
Article
Immunology
Ahmed I. I. El-Batal, Nawal E. E. Al-Hazmi, Ayman A. A. Farrag, Mohamed A. A. Elsayed, Ahmed M. M. El-Khawaga, Gharieb S. S. El-Sayyad, Aliaa A. A. Elshamy
Summary: Magnesium ferrite nanoparticles were synthesized and stabilized with citric acid, and then loaded with Amoxicillin. The nanocomposites showed significant antimicrobial and antibiofilm activities against various pathogenic microbes, as well as excellent disinfection effects under UV illumination.
MICROBIAL PATHOGENESIS
(2022)
Article
Chemistry, Multidisciplinary
Abeer A. El-Sisi, Mohamed Ali, Sohair F. Ramdan, Osama AlTaweel, Ahmed I. A. Abd El-Mageed, Ahmed A. El-Sherif
Summary: A series of thiosemicarbazone compounds were synthesized and characterized. The thermodynamics and protonation constants of one representative compound, TSC1, were calculated and discussed. The solution speciation of different species was studied at different pH levels. The synthesized compound, TSC1, was found to have potential as an antifungal agent, which is significant in the field of antimicrobial chemistry.
JOURNAL OF CHEMISTRY
(2022)
Article
Multidisciplinary Sciences
Ahmed M. El-Khawaga, Hesham Tantawy, Mohamed A. Elsayed, Ahmed I. A. Abd El-Mageed
Summary: This study presents the synthesis and doping of reduced graphene oxide with porphyrin nanoparticles to fabricate a nanocomposite material. The nanocomposite showed excellent removal activity of azo dye and antimicrobial potential. The findings indicate the significant potential of the nanocomposite in pollutant dye removal and antibacterial/antifungal properties.
SCIENTIFIC REPORTS
(2022)
Article
Multidisciplinary Sciences
M. Abd Elkodous, Ahmed M. El-Khawaga, Marwa Mohamed Abouelela, M. I. A. Abdel Maksoud
Summary: The pollution and unequal distribution of fresh water are causing a water scarcity crisis. Therefore, it is crucial to develop cost-effective and efficient techniques for water purification.
SCIENTIFIC REPORTS
(2023)
Article
Multidisciplinary Sciences
Ahmed M. El-Khawaga, Mohamed A. Elsayed, Yosri A. Fahim, Rasha E. Shalaby
Summary: In this study, CoFe2O4 nanoparticles were prepared and coated with Capsaicin. The characteristics of the modified nanoparticles were examined. The antimicrobial potential and photocatalytic degradation abilities were investigated using Fuchsine basic. Results showed that the coated nanoparticles displayed higher antimicrobial activity against Gram-positive bacteria and exhibited efficient photocatalytic degradation of Fuchsine basic at pH 9.0.
SCIENTIFIC REPORTS
(2023)
Article
Polymer Science
Ahmed I. A. Abd El-Mageed, Takuji Ogawa
Summary: Through microscopic imaging techniques, this study successfully identified the supramolecular structure of porphyrin polymers on carbon nanotubes, showing a preference for coplanar well-ordered arrangements. This finding is significant for further understanding, designing, and fabricating novel supramolecular architectonics of porphyrin/SWNT-based devices.
Review
Chemistry, Physical
Osama H. Abuzeyad, Ahmed M. El-Khawaga, Hesham Tantawy, Mohamed A. Elsayed
Summary: Agricultural, residential, and industrial activities have negative impacts on the environment, leading to significant changes such as global warming and wastewater pollution. The pollution of wastewater poses a risk to public health, thus necessitating the treatment of persistent contaminants. While traditional methods have limitations, the use of rGO/GO-based composite systems has shown promise in addressing this issue. These composites exhibit higher activity for redox reactions and photocatalytic processes due to the synergistic interactions between their components.
JOURNAL OF MOLECULAR STRUCTURE
(2023)
Review
Biochemistry & Molecular Biology
Doaa S. R. Khafaga, Ahmed M. El-Khawaga, Rehab Abd Elfattah Mohammed, Heba K. Abdelhakim
Summary: This review presents an effective strategy of using a drug delivery system with nanoparticles produced through a biological system to enhance the anticancer impact of drugs, including sorafenib. The development of intelligent nano formulations of sorafenib has been focused on to improve its targeting ability and bioavailability. The use of certain magnetic nanoparticle materials as carriers for the medicine can minimize drug administration and avoid impacting normal cells.
MOLECULAR BIOLOGY REPORTS
(2023)
Article
Multidisciplinary Sciences
Sherif Elbasuney, Ahmed M. El-Khawaga, Mohamed A. Elsayed, Amir Elsaidy, Miguel A. Correa-Duarte
Summary: Hydroxyapatite (HA), the most common bioceramic material, is a promising catalyst support. Highly crystalline and mono-dispersed silver doped hydroxyapatite (Ag-HA) nanorods of 60 nm length were successfully synthesized through hydrothermal processing. The silver dopant improved chemisorption for crystal violet (CV) contaminant and enhanced the negative charge on the catalyst surface, leading to enhanced chemisorption of positively charged contaminants. Ag-HA nanocomposite showed high activity against Gram-positive bacteria and inhibited biofilm formation, making it a potential green bioceramic photocatalyst for wastewater treatment.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Multidisciplinary
Al-Shymaa Y. Mohammed, Amro K. F. Dyab, Fouad Taha, Ahmed I. A. Abd El-Mageed
Summary: This study explored the feasibility of encapsulating aspirin into Lycopodium clavatum L. sporopollenin microcapsules, and characterized the physico-chemical features of sporopollenin, pure aspirin, and sporopollenin loaded with aspirin. The controlled in vitro release of aspirin in a gastrointestinal environment was demonstrated.
Article
Chemistry, Multidisciplinary
M. Abd Elkodous, Ahmed M. El-Khawaga, M. I. A. Abdel Maksoud, Gharieb S. El-Sayyad, Nurhaswani Alias, Hazem Abdelsalam, Medhat A. Ibrahim, Mohamed A. Elsayed, Go Kawamura, Zainovia Lockman, Wai Kian Tan, Atsunori Matsuda
Summary: Due to modern industrialization and population growth, access to clean water has become a global challenge. In this study, a metal-semiconductor heterojunction was constructed between Cu NPs and the Co0.5Ni0.5Fe2O4/SiO2/TiO2 composite matrix for the photodegradation of potassium permanganate, hexavalent chromium Cr(vi) and p-nitroaniline (pNA) under UV light. The study also evaluated the electronic and adsorption properties after Cu loading and investigated the antimicrobial properties of the prepared samples.
Article
Chemistry, Physical
Xinlei Chen, Shiyi Chen, Xuele Lin, Jingxuan Zhou, Xingjun Gao, Yaoqi Zhen, Xiaodan Ma, Shouwen Jin, Linfang Shi, Hui Liu, Daqi Wang
Summary: Nine mixed-ligand Cd2+ complexes with different geometric structures were synthesized and characterized. The complexes exhibit various coordination modes and form both intra- and intermolecular hydrogen bonds.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Rupali Mahajan, Abhishek Sharma, Bhagyashree Patra, Lijo Mani, Parul Grover, Sandeep Kumar, Santosh Kumar Guru, Gananadhamu Samanthula, Amol G. Dikundwar, Amit Asthana
Summary: This research article provides a comprehensive characterization and toxicological assessment of a photoisomeric impurity of the antianemic drug Roxadustat. The impurity has a distinct structure compared to the drug and its formation due to light exposure is a concern. Through various experiments, including single crystal XRD, physicochemical characterization, and in vitro cytotoxicity assays, the researchers confirmed the structure of the impurity, evaluated its conversion with Roxadustat, and assessed its toxicological activity. These findings contribute to the understanding of drug stability, safety, and formulation development.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Laila S. Alqarni, Azzah M. Alghamdi, Nuha Y. Elamin, A. Rajeh
Summary: The solution casting method was used to produce a new type of nanocomposites made of chitosan, gelatin, and co-doped ZnO nanoparticles. The addition of 3.5% co-doped ZnO nanoparticles improved the physicochemical characteristics and antimicrobial effects of the nanocomposites, indicating their significant potential in food packaging and energy storage.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Ruchi Gaur
Summary: The structure and intermolecular interactions of a newly synthesized bis-chalcone THXA were studied using experimental and computational methods. The importance of non-covalent interactions such as pi center dot center dot center dot pi, C-H center dot center dot center dot S, and C-H center dot center dot center dot pi was revealed.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Andrii Bazylevich, Leonid Patsenker, Sarit Aviel-Ronen, Gary Gellerman
Summary: Drug combination therapy is commonly used for treating various skin disorders, but its effectiveness is often limited. In this study, researchers synthesized conjugates of anti-pigmenting drugs and hyaluronic acid (HA) to improve treatment efficacy. These HA-drug conjugates exhibited measurable drug release profiles and demonstrated superior depigmentation effects compared to control groups in a swine model.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Xiaodan Ma, Xinlei Chen, Yaoqi Zhen, Xunjie Zheng, Chengzhe Shi, Shouwen Jin, Bin Liu, Bin Chen, Daqi Wang
Summary: Cocrystallization experiments between minoxidil and aryl acids coformers resulted in the successful formation of multi-component samples. The nature of these samples was determined using various techniques and their structural and supramolecular aspects were investigated. The outcomes revealed the importance of nonbonding contacts and different types of interactions in stabilizing and expanding the crystal structures.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Najla A. Alshaye, Magdy A. Ibrahim, Al-Shimaa Badran
Summary: The chemical behavior of 3-substituted-6,8-dimethylchromones towards phenylhydrazine was examined. Different reaction conditions produced various products, and the molecular geometries and reactivity descriptors of the compounds were also investigated. The results suggest that these compounds are suitable for nonlinear optical applications.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Hayette Alliouche, Houria Bouria, Rafik Bensegueni, Mounia Guergouri, Abdelmalek Bouraiou, Ali Belfaitah
Summary: In this paper, a combined experimental and theoretical study was conducted to synthesize and characterize new 2-quinolone-piperidine and -morpholine hybrids. The results from experiments were validated using computational calculations, and the affinity between these compounds and Acetylcholinesterase/Butyrylcholinesterase was estimated through molecular docking.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Wei-Min Chen, Juan-Juan Shao, Yi Zhang, Zhen-Dong Xue, Peng-Lai Liu, Jian-Ling Ni, Li-Zhuang Chen, Qiang Gao, Fang-Ming Wang
Summary: This study synthesized and characterized a novel Mn-based LMOF, and achieved good results in detecting heavy metal Al3+ in water, showing good stability, high selectivity and sensitivity. This provides new insights into the potential applications of Mn-based MOFs in chemical sensing.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Jun-Xia Li, Yi-Jing Lu, Ke-Ying Quan, Li-Bing Wu, Xun Feng, Wei-Zhou Wang
Summary: This study synthesized two cobalt(II) complexes and analyzed their crystal structures using single-crystal X-ray diffraction. The results showed that the crystal structures of these complexes were different, and they exhibited different crystal packing and magnetic properties.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Yang Li, Yan Zhang, Hong Xu, Min Li, Zhen Li, Zi-yu Song, Ji-shi Chen, Yan-Jun Liu, Yong Sun, Zhao Yang
Summary: This study reports the synthesis and solid-state characterization of a new pharmaceutical cocrystal, PRO-BPE, which can enhance the solubility of the highly water-insoluble prodrug probenecid. The PRO-BPE cocrystals were found to have superior water solubility compared to pure PRO. This research provides valuable insights into improving the solubility of poorly soluble drugs.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Lucas G. B. Felicio, Bianca B. M. Vieira, Ivana S. Lula, Renata Diniz, Frank Alexis, Flavio B. Miguz, Frederico B. De Sousa
Summary: A novel spiropyran derivative was synthesized for heavy metals sensing in water. The results demonstrated that the new derivative can serve as a rapid, sensitive, and simple tool for detecting Hg2+ ions in water with high selectivity.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Junqing Meng, Jie Wang, Lijuan Wang, Chunhui Lyu, Haiyan Chen, Yingpei Lyu, Baisheng Nie
Summary: Material modification with low surface energy can achieve lower surface free energy on micro-and nano-rough structures, which is crucial for developing superhydrophobic surfaces. In this study, attapulgite (APT) was modified with alkylamine, alkylammonium salt, and stearic acid, and the interaction between low surface materials and attapulgite was explained. The results showed that the hydrophobicity of APT was significantly modified by the modifiers, and the surface free energy of the composites first decreased and then increased with increasing molecular number of low surface energy monomers.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Karan Goswami, Dipak Das, Parthasarathi Bera, Sounak Roy, Md. Motin Seikh, Prasanta Kumar Sinha, Arup Gayen
Summary: This work presents the development of a simple and highly active heterogeneous Pd catalyst for Suzuki-Miyaura carbon-carbon cross-coupling reaction. The NiPdFe-1 catalyst shows the best activity and stability among the prepared catalysts. It efficiently promotes the coupling reaction between aryl bromide and phenyl boronic acid under mild reaction conditions with high isolated yields.
JOURNAL OF MOLECULAR STRUCTURE
(2024)
Article
Chemistry, Physical
Ekta Pardhi, Devendra Singh Tomar, Rahul Khemchandani, Gananadhamu Samanthula, Pankaj Kumar Singh, Neelesh Kumar Mehra
Summary: The main aim of this study was to prepare a drug-drug coamorphous system to improve the physiochemical properties, solubility and stability of Apremilast and Indomethacin. Various solid-state characterization techniques were used to characterize the prepared system. Molecular level interactions were studied using molecular modeling and ATR-FTIR and 1H NMR. Solubility and dissolution studies showed the benefits of the coamorphous system. The system was found to be stable for a period of five months. Permeation study also demonstrated improved flux for both drugs compared to their crystalline forms. The coamorphous system showed anti-psoriatic and anti-melanogenic activity based on molecular docking results. Overall, the developed CAM-based supersaturated system exhibited improved physicochemical properties and physical stability.
JOURNAL OF MOLECULAR STRUCTURE
(2024)