Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 639, Issue -, Pages 160-170Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2023.02.050
Keywords
Biomass-derived carbon; Magnetic particle; Microwave absorption; Ultra-thin matching thickness; Polarization loss
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This study presents a two-step procedure for preparing wrinkle-like multilayer biomass-derived composites with magnetic Co particles and ZnO particles. The synergistic effect of the wrinkle-like multilayer structure and Co and ZnO particles, as well as the existence of heterogeneous interfaces, leads to strong microwave absorption properties.
Biomass-carbon materials have excellent electromagnetic wave attenuation properties, which is one of the essential factors for developing ultra-thin matched-thickness, and high-performance microwave absorption materials. This study reports a two-step procedure consisting of carbonization and subsequent in-situ growth for preparing a wrinkle-like multilayer biomass-derived composites with magnetic Co particles and ZnO particles (CoZnO/C-X). The synergistic effect of a wrinkle-like multilayer structure and Co and ZnO particles, as well as the existence of many heterogeneous interfaces in the composites structure, and efficiently creates multiple scattering and reflections, which gives the composites the strong microwave absorption properties. The minimum reflection loss value (RLmin) of CoZnO/C-X reaches - 54.90 dB with a thickness of 1.8 mm, and the effective absorption bandwidth (lower than - 10 dB) is 7.2 GHz covering from 10.8 GHz to18.0 GHz with matching thickness of 2.0 mm. Furthermore, the reasonable dielectric/magnetic losses, optimized impedance matching and enhanced polarization loss play an indispensable role among improving microwave absorption performance. Thus, this result provides a good potential method for preparation of magnetic particle/metal oxide/ biomass-derived carbon microwave absorbing structural materials.(c) 2023 Elsevier Inc. All rights reserved.
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