Journal
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
Volume 61, Issue -, Pages 20-25Publisher
ELSEVIER
DOI: 10.1016/j.jtice.2015.11.025
Keywords
Hierarchical catalysts; Dealumination; Hexane cracking; Mordenite; On-purpose propylene
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Funding
- King Abdulaziz City for Science and Technology (KACST) through the Science & Technology Unit at King Fahd University of Petroleum & Minerals (KFUPM), National Science, Technology and Innovation Plan [13-NAN1702-04]
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Cost-effective and efficient catalysts for pyrolysis and catalytic cracking can be derived from low-cost and abundantly available natural minerals. Herein, we report the fabrication of hierarchical mordenite (MOR) zeolites with an enhancement in micropore properties, which were obtained by ion exchange followed by dealumination of natural zeolites. Crystallinity, textural properties and morphologies of the hierarchical catalysts were characterized by using X-ray diffraction (XRD), nitrogen physisorption and field-emission scanning electron microscopy (SEM). The XRD patterns show that the parent minerals contain natural mordenite as the dominant phase (73-83 wt%). The severity of the dealumination was studied by applying different concentrations of nitric acid (HNO3). Dealumination affected crystallinity, Si/Al ratio, mesoporosity of mordenite, and selectivity of products in n-hexane cracking. Crystallinity of hierarchical MOR decreased with higher HNO3 concentrations. High selectivity to propylene with propylene/ethylene ratio of 1.26 was achieved over mordenite treated with mild dealumination by HNO3 (1 M). These cost-effective catalysts derived from natural zeolites are potentially applied in chemical industries. (C) 2015 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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