4.7 Article

Preparation and characterization of sodium potassium niobate-silver niobate lead-free films by chemical solution deposition

Journal

CERAMICS INTERNATIONAL
Volume 41, Issue -, Pages S228-S233

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2015.03.268

Keywords

KNN - AN films; Chemical solution deposition method; Electrical properties

Funding

  1. International Science & Technology Cooperation Program of China [2011DFA51880]
  2. 111 Project of China [B14040]
  3. National Natural Science Foundation of China [90923001]
  4. Shaanxi Province International Collaboration Program [2009KW-12, 2010KW-09]
  5. Shaanxi Science & Technology Promotion Program [2011TG-08]
  6. Chinese Ministry of Education
  7. Chinese Government
  8. Natural Science and Engineering Research Council of Canada (NSERC)

Ask authors/readers for more resources

Lead-free ferroelectric 0.82K(0.5)Na(0.5)NbO(3)-0.18AgNbO(3) (KNN - AN) films were successfully synthesized by a chemical solution deposition (CSD) method. In particular, silver acetate was dissolved in 2-methoxyethanol with the aid of nitric acid and molecular sieve was used to remove residual moisture in the precursor solution at room temperature. The effects of the thickness on the structures and electrical properties of the KNN-AN films were systematically investigated. The KNN AN film with the thickness of 2.53 mu m showed good dielectric properties and well saturated polarization-electric field hysteresis loops. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Ceramics

Structure and properties of Bi(Zn1/2Ti1/2)O3-modified Pb(Zr,Ti)O3 piezo-/ferroelectric ceramics around the ternary morphotropic phase boundary

Yujuan Xie, Bi-Xia Wang, Neha Claire, Zuo-Guang Ye

Summary: A Bi(Zn1/2Ti1/2)O-3-PbZrO3-PbTiO3 ternary solid solution was synthesized to develop high-performance piezo-/ferroelectric materials, with the best properties found in the y = 0.15 series. This series showed improved dielectric constant, remnant polarization, Curie temperature, and coercive field, making it a promising material for high-power piezoelectric applications.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2022)

Article Chemistry, Physical

Reliable Ge2Sb2Te5 based phase-change electronic synapses using carbon doping and programmed pulses

Qiang Wang, Gang Niu, Ruobing Wang, Ren Luo, Zuo-Guang Ye, Jinshun Bi, Xi Li, Zhitang Song, Wei Ren, Sannian Song

Summary: This study presents significant enhancements in PCRAM electronic synapses based on materials engineering and pulse programming. The controllability of conductance is increased through carbon doping, while non-linear programmable pulse excitations lead to reliable synaptic potentiation and depression. Improved programmable pulse schemes are demonstrated, showing potential advantages in flexible programming and reliable data collection.

JOURNAL OF MATERIOMICS (2022)

Article Chemistry, Multidisciplinary

Self-Assembled Epitaxial Ferroelectric Oxide Nanospring with Super-Scalability

Guohua Dong, Yue Hu, Changqing Guo, Haijun Wu, Haixia Liu, Ruobo Peng, Dan Xian, Qi Mao, Yongqi Dong, Yanan Zhao, Bin Peng, Zhiguang Wang, Zhongqiang Hu, Junwei Zhang, Xueyun Wang, Jiawang Hong, Zhenlin Luo, Wei Ren, Zuo-Guang Ye, Zhuangde Jiang, Ziyao Zhou, Houbing Huang, Yong Peng, Ming Liu

Summary: This study presents a method for preparing self-assembled, epitaxial, ferroelectric nanosprings and demonstrates their super-scalability and full recovery capability.

ADVANCED MATERIALS (2022)

Review Chemistry, Multidisciplinary

High Curie temperature bismuth-based piezo-/ferroelectric single crystals of complex perovskite structure: recent progress and perspectives

Zenghui Liu, Hua Wu, Jian Zhuang, Gang Niu, Nan Zhang, Wei Ren, Zuo-Guang Ye

Summary: Bismuth-based piezo-/ferroelectric single crystals (BPSCs) show promising potential for high-temperature electromechanical applications due to their excellent piezoelectric performance and high Curie temperature. Recent research has focused on materials design, crystal growth, physical properties, crystal chemistry, and complex domain structures of BPSCs, providing a positive outlook for future applications.

CRYSTENGCOMM (2022)

Article Acoustics

Effects of Composition Segregation in PMN-PT Crystals on Ultrasound Transducer Performance

Zibo Jiang, Chenxue Hou, Chunlong Fei, Zhaoxi Li, Zuo-Guang Ye

Summary: This study investigates the relationship between composition segregation and ultrasonic transducer performance in lead magnesium niobate-lead titanate (PMN-PT) single crystals. The results show that changes in crystal composition significantly affect the piezoelectric coefficient and relative permittivity, but have minimal impact on the transducer bandwidth and center frequency. By using crystals of different compositions, similar transducer performance can be achieved, reducing material costs.

IEEE TRANSACTIONS ON ULTRASONICS FERROELECTRICS AND FREQUENCY CONTROL (2022)

Article Multidisciplinary Sciences

Highly heterogeneous epitaxy of flexoelectric BaTiO3-δ membrane on Ge

Liyan Dai, Jinyan Zhao, Jingrui Li, Bohan Chen, Shijie Zhai, Zhongying Xue, Zengfeng Di, Boyuan Feng, Yanxiao Sun, Yunyun Luo, Ming Ma, Jie Zhang, Sunan Ding, Libo Zhao, Zhuangde Jiang, Wenbo Luo, Yi Quan, Jutta Schwarzkopf, Thomas Schroeder, Zuo-Guang Ye, Ya-Hong Xie, Wei Ren, Gang Niu

Summary: In this study, the remote epitaxy of BaTiO3 on germanium using a graphene intermediate layer was demonstrated, resulting in a highly heterogeneous epitaxial system. Graphene played an important role in surface passivation. The transferred BTO3-delta films possessed enhanced flexoelectric properties.

NATURE COMMUNICATIONS (2022)

Article Materials Science, Multidisciplinary

Interfacial and microstructural changes of the Al2O3/ZnO multilayer films induced by in-situ growth and post-annealing temperatures

Ruikang Wang, Tianyi Yan, Chao Li, Wei Ren, Gang Niu, Zhuang-De Jiang, Chenying Wang, Ming Liu, Zuo-Guang Ye, Yijun Zhang

Summary: This study investigated the microstructure and solid-state reaction of Al2O3/ZnO nanolaminates using atomic layer deposition and post-annealing. The results show that the growth temperature and post-annealing temperature not only affect the crystallinity and preferred orientation of the nanocomposites, but also influence the interfacial diffusion and counter-diffusion of atoms, thereby affecting the solid-state reaction.

MATERIALS CHEMISTRY AND PHYSICS (2022)

Article Physics, Applied

Lead free 0.9Na1/2Bi1/2TiO3-0.1BaZr0.2Ti0.8O3 thin film with large piezoelectric electrostrain

Hao Yang, Jinyan Zhao, Wei Ren, Zuo-Guang Ye, K. B. Vinayakumar, Rosana A. Dias, Rui M. R. Pinto, Jian Zhuang, Nan Zhang

Summary: A sodium bismuth titanate-based thin film was prepared using the sol-gel spin coating method, which showed low dielectric loss and high remnant polarization. The film exhibited stable piezoelectric response at higher temperatures, and the fabricated piezoelectric device demonstrated a large macro-scale strain value.

APPLIED PHYSICS LETTERS (2022)

Review Materials Science, Multidisciplinary

Recent progress in bismuth-based high Curie temperature piezo-/ferroelectric perovskites for electromechanical transduction applications

Zenghui Liu, Hua Wu, Yi Yuan, Hongyan Wan, Zeng Luo, Pan Gao, Jian Zhuang, Jie Zhang, Nan Zhang, Jingrui Li, Yage Zhan, Wei Ren, Zuo-Guang Ye

Summary: This article reviews the recent progress in bismuth-based piezo-/ferroelectric perovskite materials, including material synthesis, doping effects, and chemical modifications. It also presents the developments of these materials for high-temperature electromechanical transduction applications and proposes possible solutions to existing issues.

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE (2022)

Article Chemistry, Physical

Optimizing strain response in lead-free (Bi0.5Na0.5)TiO3-BaTiO3- NaNbO3 solid solutions via ferroelectric / (non-)ergodic relaxor phase boundary engineering

Zhe Wang, Jinyan Zhao, Nan Zhang, Wei Ren, Kun Zheng, Yi Quan, Jian Zhuang, Yijun Zhang, Luyue Jiang, Lingyan Wang, Gang Niu, Ming Liu, Zhuangde Jiang, Yulong Zhao, Zuo-Guang Ye

Summary: Lead-free bismuth sodium titanate (BNT) ceramics with a composition of x = 3.5 demonstrate a large strain response of 0.61%. The coexistence of ferroelectric and relaxor domain structures, along with the substitution of antiferroelectric NN, contribute to the enhanced strain response. This study provides new insights into the interplay between mesoscopic domains and macroscopic electrical properties in BNT-based piezoceramics.

JOURNAL OF MATERIOMICS (2023)

Article Materials Science, Multidisciplinary

Design and development of outstanding strain properties in NBT-based lead-free piezoelectric multilayer actuators by grain-orientation engineering

Kai Liu, Fafu Liu, Wu Zhang, Zhanming Dou, Weigang Ma, Chanatip Samart, Naohisa Takesue, Hua Tan, Pengyuan Fan, Zuo-Guang Ye, Haibo Zhang

Summary: (Na1/2Bi1/2)TiO3-based piezoelectric multilayer actuators (MLAs) have attracted attention as a replacement for lead-based piezoelectric devices due to environmental concerns. In this study, a grain orientation engineering approach was used to prepare a textured NBT-based MLA with high strain output and effective co-firing. The textured MLA achieved a high texturing degree and significantly higher strain performance compared to the non-textured counterpart. The effects of grain orientation engineering on mechanical properties and fracture behavior were analyzed.

ACTA MATERIALIA (2023)

Article Chemistry, Physical

Structure, Antiferroelectricity and Energy-Storage Performance of Lead Hafnate in a Wide Temperature Range

Vidhi Chauhan, Bi-Xia Wang, Zuo-Guang Ye

Summary: In this study, high-quality PbHfO3 ceramics were prepared via solid-state synthesis and its characteristics were investigated. It was found that PbHfO3 exhibited orthorhombic structure with antiparallel alignment of Pb2+ ions along the [001] directions. The polarization-electric field (P-E) relation of PbHfO3 at room temperature and in the intermediate phase temperature range were measured. The results showed that PbHfO3 had a high recoverable energy-storage density and efficiency at both room temperature and intermediate phase temperature.

MATERIALS (2023)

Article Materials Science, Multidisciplinary

Hierarchical compositional ordering in lead-based perovskite relaxors

Yanxing Zhang, Jiale Zhang, Nan Zhang, Laijun Liu, Alexei A. Bokov, Zuo-Guang Ye, Dawei Wang

Summary: This study reveals a hierarchical ordering in lead-based relaxor ferroelectric perovskites, enriching our understanding of the complex nature of the chemical ordering in these materials.

PHYSICAL REVIEW B (2023)

Article Materials Science, Multidisciplinary

Origin of polar nanoregions from displacive correlation in relaxor ferroelectric Pb(Mg1/3Nb2/3)O3-PbTiO3

Zhen Wang, Zheyi An, Jian Zhuang, Fei Li, Wei Ren, Zuo-Guang Ye, Nan Zhang

Summary: In this study, neutron atomic pair distribution function (PDF) analysis was used to investigate the local-structural features of relaxor-ferroelectric materials at low temperatures. The results revealed that the existence of polar nanoregions (PNRs) is characterized by strong displacement correlation rather than structural symmetry. This finding provides a better understanding of the high-performance piezoelectric properties of these materials.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Materials Science, Multidisciplinary

High energy storage capacity, heterogeneous domain structure and stabilization of intermediate phase in PbZrO3-based antiferroelectric single crystals

Zenghui Liu, Zhixuan Guo, Hongyan Wan, Yi Yuan, Hao Yang, Hua Wu, Wei Ren, Zuo-Guang Ye

Summary: Lead zirconate (PZ)-based antiferroelectric (AFE) materials have limitations due to their ultrahigh critical electric field (EF). To overcome this, a bismuth-based perovskite, Bi(Zn2/3Nb1/3)O-3 (BZN), was introduced to PZ to form the PZ-BZN solid solution. Single crystals of this system were grown and investigated, revealing improved energy storage performance and a better understanding of the domain structure and origin of the intermediate (IM) phase in PZ-based AFE materials.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

No Data Available