4.7 Article

AC conductivity and dielectric properties of (Bi,Na)TiO3-BaTiO3 lead free ceramics

Journal

CERAMICS INTERNATIONAL
Volume 41, Issue 5, Pages 6925-6932

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2015.01.147

Keywords

Dielectric properties; Electrical conductivity; Lead free; Piezoelectric; X-ray diffraction

Funding

  1. National Research Foundation of Korea (NRF) grant - Korean Government [NRF-2013R1A1A2009856]

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(Bi,Na)TiO3 (BNT) based ceramics have been extensively investigated for electronic device applications. BNT is ferroelectric material with ABO(3) perovskite structure. BNT ceramics have high Curie temperature (T-c = 320 degrees C) and remanent polarization (P-r=38 mu C/cm(2)). Despite its relatively high coercive field (E-c=7.3 kV/mm) and low piezoelectric constant (d(33)=83 pC/N). Temperature and frequency dependent relative dielectric permittivity and loss tangent can play an important role in the device performance. To analyze the dielectric characteristics across wide temperature (303-403 K) and frequency range (1 kHz to 3 MHz), AC conductivities of (1-x)(Bi0.5Na0.5TiO3)-x(BaTiO3) (x=0, 0.02, 0.04, 0.06, 0.08, or 0.10) were measured and analyzed. The conduction mechanism was evaluated through simulations and calculations based on an Arrhenius-type equation. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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