4.7 Article

Solvothermal fabrication of three-dimensionally sphere-stacking Sb-SnO2 electrode based on TiO2 nanotube arrays

Journal

CERAMICS INTERNATIONAL
Volume 41, Issue 7, Pages 8723-8729

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2015.03.092

Keywords

Solvothermal; Sphere-stacking Sb-SnO2; TiO2 nanotube arrays

Funding

  1. National Natural Science Foundation of China [51179033, 21476053]
  2. Doctoral Program of the Ministry of Education [20132304110027]
  3. Fundamental Research Funds for the Central Universities [HEUCF201403019]
  4. Fundamental Research Operating Expense for the Central Universities [HEUCFD1417]

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TiO2-NTs-based Sb-SnO2 electrode with three-dimensiorially sphere-stacking structure was successfully fabricated by the solvothermal method, followed by annealing at 500 degrees C for 1 h. The physico-chemical properties of electrodes were characterized through scanning electron spectroscopy (SEM), X-ray diffraction (XRD) and electrochemical measurements. SEM result showed that TiO2-O2NTs/Sb-SnO2 electrode has morphology of vertically sphere-stacking coralline. Compared with Ti/Sb-SnO2, TiO2-NTs/Sb-SnO2 electrode has smaller grain size and greater specific surface area which can provide with more active sites. Compared with Ti/Sb-SnO2 electrode, TiO2-NTs/Sb-SnO2 has a higher oxygen evolution potential and stronger phenol oxidation peak, indicating an improved catalytic activity for phenol degradation. The kinetic analysis of electrochemical phenol degradation showed that the first-order kinetics rate constant on TiO2-NTs/Sb-SnO2 electrode is 1.33 times as much as that on Ti/Sb-SnO2, confirming that the sphere-stacking Sb-SnO2 based on TiO2 nanotube has a good electrocatalytic activity. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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