Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 163, Issue 13, Pages B567-B572Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0361613jes
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Funding
- National key RD program [2016YFB0402703]
- National Nature Science Foundation of China [61301045, 61401306, 61504096]
- Natural Science Foundation of Tianjin [13JCZDJC36000, 15JCYBJC24000, 16JCTPJC50800, 16JCYBJC16300]
- Youth Top-notch Talents Program of Tianjin
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A highly selective electrochemical sensor was developed for the simultaneous determination of ascorbic acid (AA), dopamine (DA), uric acid (UA), tryptophan (Trp) and nitrite using a glassy carbon electrode (GCE) modified with an Au nanoparticle/TiO2 nanoparticle/carbon nanotube (Au/TiO2/CNT) composite. The Au/TiO2/CNT nanocomposite as a sensitive layer was used because it offers great electrocatalytic activity, large surface area, and abundant active sites. The Au/TiO2/CNT nanocomposite has good selectivity and remarkable sensitivity and could determine AA, DA, UA, Trp and nitrite. The Au/TiO2/CNT/GCE had linear response ranges for detecting AA, DA, UA, Trp and nitrite of 3-281, 0.3-15, 1-162, 1-162 and 4-225 mu M, respectively. The detection limits were 1, 0.2, 0.6, 0.8 and 3 mu M, respectively. In addition, a flexible sensing paper can be prepared via these nanocomposites for the simultaneous determination of these five species. (C) 2016 The Electrochemical Society.
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