4.0 Article

PhotoMetrix: An Application for Univariate Calibration and Principal Components Analysis Using Colorimetry on Mobile Devices

Journal

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
Volume 28, Issue 2, Pages 328-335

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.5935/0103-5053.20160182

Keywords

univariate calibration; principal components analysis; colorimetry

Funding

  1. Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq)
  2. Fundacao de Amparo a Pesquisa do Estado do Rio Grande do Sul (FAPERGS)
  3. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES)
  4. Fundo de Apoio a Pesquisa da UNISC (FAP-UNISC)

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This article describes the development of a mobile colorimetric analysis tool. The application, called PhotoMetrix, employs the techniques of simple linear correlation for univariate analysis and principal components analysis (PCA) for multivariate exploratory analysis. The image data are captured by the main camera of the device and converted into red, green and blue (RGB) histograms. As regards the application, the iron determinations were performed in vitamin supplements (univariate module) and differentiation of banknotes was performed by PCA (multivariate module). For the iron determinations, three samples of vitamins at concentrations of 14, 40 and 50 mg of iron per tablet were tested and the results were not statistically significant (p > 0.05) compared to the reference method. The differentiation of banknotes was performed on Brazilian and Argentinean banknotes. The results showed clustering of the same types of banknotes, and through the loadings graph it was possible to observe the variables through the formation of clusters.

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