Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 1, Pages 91-94Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b11867
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Funding
- NSFC [21672168, 21472146]
- Ministry of Science and Technology of PRC [2014CB548200]
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Convenient silylborane precursors for introducing N,B-bidentate boryl ligands onto transition metals were designed, prepared, and employed in ready formation of irdium(III) complexes via Si-B oxidative addition. A practical, efficient catalytic ortho-borylation reaction of arenes with a broad range of directing groups was developed using an in situ generated catalyst from the silylborane preligand 3c and [IrCl(COD)](2).
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