Article
Nanoscience & Nanotechnology
William Arnold, Varun Shreyas, Yang Li, Milinda Kalutara Koralalage, Jacek B. Jasinski, Arjun Thapa, Gamini Sumanasekera, Anh T. Ngo, Badri Narayanan, Hui Wang
Summary: Solid-state lithium metal batteries with novel solid electrolytes have the potential for high energy density and safety. Sulfide-based argyrodite-class solid electrolytes are attractive due to their excellent ionic conductivity. This study synthesized F-doped argyrodites with dual dopants using a solvent-based approach and found that Li6PS5F0.5Cl0.5 exhibited the highest Li-ion conductivity and cycling performance at room temperature. The enhanced interfacial stability of Li6PS5F0.5Cl0.5 was attributed to the formation of a stable solid electrolyte interphase containing conductive species.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Multidisciplinary Sciences
Dewu Zeng, Jingming Yao, Long Zhang, Ruonan Xu, Shaojie Wang, Xinlin Yan, Chuang Yu, Lin Wang
Summary: The interfacial stability of lithium metal is crucial for the development of all-solid-state batteries. In this study, researchers investigate the influence of chloride distribution and cooling process on the evolution of the Li|SE interface microstructure. They found that controlling these factors can lead to the formation of a LiCl-rich interphase layer, which improves battery cycling performance.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Yuvaraj Subramanian, Rajesh Rajagopal, Sung Kang, Kwang-Sun Ryu
Summary: This study improved the interface stability of Li-argyrodites through metal and oxygen substitution, and evaluated their structural and electrochemical performances. The results showed that MoO2 substitution can enhance critical current density and ionic conductivity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Meng Wang, Yongqiang Han, Mo Chu, Lin Chen, Meng Liu, Yijie Gu
Summary: The effects of cerium doping and the formation of layered-spinel hetero-structure on the electrochemical properties of lithium-rich cathode material were studied. Cerium doping and formation of spinel phase facilitated lithium ion diffusion and inhibited structural collapse during cycling, leading to improved cycling stability and rate capability.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Review
Chemistry, Multidisciplinary
Gang Su, Xin Zhang, Min Xiao, Shuanjin Wang, Sheng Huang, Dongmei Han, Yuezhong Meng
Summary: This review discusses the key indicators of solid polymer electrolytes and the design strategies to improve their properties. It also explores adjustment strategies of quasi-solid-state polymer electrolytes. The aim is to provide researchers with a general perspective of solid polymer electrolytes and stimulate more extensive interests in high-performance lithium-ion batteries.
Article
Multidisciplinary Sciences
Hye-Jin Park, Seong-Ju Sim, Bong-Soo Jin, Seung-Hwan Lee, Hyun-Soo Kim
Summary: In this study, a method for synthesizing high-energy cathode material LiNi0.93Co0.04Al0.03O2 (NCA) by the solid-phase method is presented. The sintering temperature is found to significantly affect the electrochemical performance, with the sample sintered at 720 degrees C exhibiting the best performance in terms of discharge capacity, rate capability, and cycle stability.
SCIENTIFIC REPORTS
(2022)
Article
Materials Science, Ceramics
Qiyue Luo, Chuang Yu, Chaochao Wei, Shuai Chen, Shaoqing Chen, Ziling Jiang, Linfeng Peng, Shijie Cheng, Jia Xie
Summary: Li10SnP2S12 is a solid electrolyte with ultrahigh Li-ion conductivity, which shows great potential for solid-state batteries. However, its applications are limited by the high cost of Ge and poor stability. Replacing Ge with Sn significantly reduces the cost while maintaining high conductivity, but the interface stability with high voltage cathodes is still an issue. To address this, a highly conductive Li3InCl6 electrolyte is introduced, leading to superior electrochemical performances at different temperatures.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Multidisciplinary
Zheng Li, Yuan Li, Chen-Xi Bi, Qian-Kui Zhang, Li-Peng Hou, Xi-Yao Li, Jin Ma, Xue-Qiang Zhang, Bo-Quan Li, Rui Wen, Qiang Zhang
Summary: This study constructs an organic-rich solid electrolyte interphase (SEI) to inhibit the parasitic reactions between lithium polysulfides (LiPSs) and Li metal anodes, achieving long-cycling Li-S batteries. The organic-rich SEI effectively inhibits the LiPS parasitic reactions and protects working Li metal anodes, extending the cycling lifespan of Li-S batteries.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Zhuolin Yang, Xinyu Zhang, Shijie Lu, Jianxiong Xiao, Borong Wu, Zhikun Zhao, Daobin Mu
Summary: Single-crystal nickel-rich materials show excellent structure stability and cycle performance, but high cation mixing in the cathode material negatively affects its electrochemical performance. By regulating the cation mixing, the single-crystal LiNi0.83Co0.12Mn0.05O2 cathode material exhibits high discharge capacity, excellent capacity retention, and superior rate capability. The improved performance is attributed to the reduced cation mixing and integrated single grains, allowing for rapid Li+ transportation within the crystal structure.
Article
Nanoscience & Nanotechnology
Zhao Fang, Qinghua Deng, Yang Zhou, Xiaolong Fu, Jiacheng Yi, Lizhi Wu, Qingyang Dai, Yong Yang
Summary: The study explores the use of conjugated organic polymers as platforms for solid-state polymer electrolytes (SPEs). It designs and applies three cationic COPs with different chain lengths of quaternary ammonium salts to SPEs for the first time. The COP with the longest chain length (CbzT@C9) exhibits the most attractive electrochemical performance due to its larger specific surface area, richer pore structure, and increased compatibility with other materials.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Li-Peng Hou, Xi-Yao Li, Chen-Xi Bi, Zi-Xian Chen, Zheng Li, Li-Ling Su, Peng Shi, Cheng-Bin Jin, Bo-Quan Li, Jia-Qi Huang, Xue-Qiang Zhang, Qiang Zhang
Summary: This study demonstrates the role of a lithium oxysulfide-rich solid electrolyte interphase (SEI) in shielding parasitic reactions and improving the lifespan of lithium-sulfur batteries. The SEI layer, which introduces abundant lithium oxysulfide components, effectively shields the parasitic reactions and increases the lifespan of the batteries by 60% under demanding conditions.
JOURNAL OF POWER SOURCES
(2022)
Article
Materials Science, Multidisciplinary
Jin-Yan Lin, Shuai Chen, Jia-Yang Li, Dian Yu, Xiang-Ling Xu, Chuang Yu, Shao-Qing Chen, Xue-Fei Miao, Lin-Feng Peng, Chao-Chao Wei, Chong-Xuan Liu, Shi-Jie Cheng, Jia Xie
Summary: The all-solid-state Li-Se battery shows great potential for next-generation energy storage devices due to its high energy density and safety. However, the low ionic conductivity of the solid electrolytes and large volume changes of Se active materials limit its applications. In this study, a simple solid-state reaction method is used to synthesize a chlorine-rich argyrodite Li5.5PS4.5Cl1.5 electrolyte with high conductivity. Carbon nanotubes are introduced as a host for Se to enhance electronic conductivity and reduce volume expansion. The assembled battery demonstrates excellent performance, with high discharge capacity and long cycling life at different temperatures.
Article
Nanoscience & Nanotechnology
Yuqiang Pi, Zhiwei Gan, Mengyu Yan, Zheng Li, Yushan Ruan, Cunyuan Pei, Hui Yu, Yaowen Ge, Qinyou An, Liqiang Mai
Summary: The CNTs/LiV3O8/Y2O3 cathode composite synthesized by spray-drying shows excellent Li+ storage performance in SSLMBs, with high reversible capacity, power capability, and cycle lifespan. The rechargeable solid-state Li/M-LVO-Y-2 LMB with PEO-based SPE film achieves high discharge capacity and stable cycling performance in high-temperature environments.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Satish Kumar Mylavarapu, Fulya Ulu Okudur, Saeed Yari, Dries De Sloovere, Jan D'Haen, Ahmed Shafique, Marlies K. Van Bael, Mohammadhosein Safari, An Hardy
Summary: In this study, a cost-effective chemical solution deposition route of a thin TiOx shell on LiNi0.6Mn0.2Co0.2O2 (NMC-622) particles was demonstrated to improve the electrochemical performance. Surface modification with TiOx was found to enhance rate performance and reduce charge-transfer resistance, showcasing the beneficial impact on the electrochemical performance of NMC-622 positive electrodes in lithium-ion battery applications.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Yaqi Hu, Zhen Sun, Zongliang Zhang, Siliang Liu, Fangbo He, Yang Liu, Zhi Zhuang, Fangyang Liu
Summary: This study investigates the use of a sulfide cathode active material Li2TiS3 that is chemically compatible with sulfide solid electrolytes in all-solid-state lithium batteries. The batteries show high discharge capacity and good capacity retention at room temperature, and the Li6PS5Cl electrolyte also contributes to additional capacity. The potential of Li2TiS3 material for practical applications is explored.
ADVANCED ENERGY MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Linfeng Peng, Chuang Yu, Ziqi Zhang, Ruonan Xu, Mengjun Sun, Long Zhang, Shijie Cheng, Jia Xie
Summary: Solid electrolytes play a crucial role in the fabrication of effective interfaces in solid-state batteries. By tuning the electrolyte distribution with varied particle sizes, solid-state batteries with excellent performance at different operating temperatures can be constructed.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Wei Zhang, Fenfen Ma, Qiang Wu, Ziqi Zeng, Wei Zhong, Shijie Cheng, Xin Chen, Jia Xie
Summary: A dual-functional electrolyte additive, diphenyl ditelluride (DPDTe), was reported for lithium-sulfur batteries. It acts as a redox mediator for accelerating the redox kinetics of sulfur and reacts with lithium metal to form a stable solid-electrolyte interphase (SEI). The lithium-sulfur battery with DPDTe shows remarkable cycling stability and high-rate performance.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Han Zhang, Ziqi Zeng, Fenfen Ma, Xinlan Wang, Yuanke Wu, Mengchuang Liu, Renjie He, Shijie Cheng, Jia Xie
Summary: Fluorinated aromatic hydrocarbons in the electrolyte enable stable cycling of high-voltage LiNi0.7Co0.1Mn0.2O2 (NCM712) and LiCoO2 (LCO) by balancing the formation of corrosive HF and LiF. The electrolyte restrains HF formation but strengthens LiF formation, leading to improved cycling stability and high Coulombic efficiency.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yuanke K. K. Wu, Ziqi Q. Q. Zeng, Sheng Lei, Mengchuang C. C. Liu, Wei Zhong, Mingsheng S. S. Qin, Shijie J. J. Cheng, Jia Xie
Summary: This study manages to inhibit the exothermic reaction in the early stage of thermal runaway (TR) by targeted repair of the solid electrolyte interface (SEI). By using 1,3,5-trimethyl-1,3,5-tris(3,3,3-trifluoropropyl)cyclotrisiloxane (D3F) as an additive, the self-exothermic and TR trigger temperatures of the battery are significantly increased.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Mingsheng Qin, Ziqi Zeng, Qiang Wu, Hui Yan, Mengchuang Liu, Yuanke Wu, Han Zhang, Sheng Lei, Shijie Cheng, Jia Xie
Summary: Developing advanced electrolytes is crucial for next-generation lithium-ion batteries. By manipulating the dipole-dipole interactions among Li+, solvents, and non-coordinating molecules, the solvation process can be improved, inhibiting solvent co-intercalation into electrodes. This strategy expands the possibilities for electrolyte design and enhances the electrochemical performance of LIBs.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Engineering, Chemical
Zhongkai Wu, Ru Wang, Chuang Yu, Chaochao Wei, Shuai Chen, Cong Liao, Shijie Cheng, Jia Xie
Summary: Sulfide electrolytes with optimized LiI doping in the Li3PS4 structure exhibit high ionic conductivities, making them promising solid electrolytes for all-solid-state batteries. These sulfide electrolytes showed stable capacities and excellent cycling performance at 0 degrees C but experienced fast capacity decay at 60 degrees C. The electrochemical performance differences at different temperatures were attributed to interfacial resistance caused by volume changes. This study provides insights into the temperature effects on the electrochemical performance of all-solid-state Li-S batteries.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Nanoscience & Nanotechnology
Rui Xi, Hao Jiang, Sergey Kustov, Zhihui Zhang, Guoqun Zhao, Kim Vanmeensel, Jan Van Humbeeck, Xiebin Wang
Summary: NiTiNb alloys were fabricated through L-PBF with powder mixtures of prealloyed NiTi and elemental Nb powders. The addition of Nb significantly altered the dependence of MTTs on L-PBF process parameters. The net effect of Nb addition is to lower MTTs, while Ni evaporation has the opposite effect. In NiTiNb3 alloys, factors that promote and suppress MTTs are almost completely compensated, resulting in a rather stable MTT despite variations in L-PBF process parameters.
SCRIPTA MATERIALIA
(2023)
Article
Materials Science, Multidisciplinary
Wei Zhong, Ce Zhang, Siwu Li, Wei Zhang, Ziqi Zeng, Shijie Cheng, Jia Xie
Summary: In this study, prelithiation of a low-voltage cathode was achieved using Mo2C catalysis and nano-Li2C2O4, resulting in significantly improved energy density of lithium-ion batteries and showing great potential for practical applications.
SCIENCE CHINA-MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Cong Liao, Chuang Yu, Shuai Chen, Chaochao Wei, Xuefei Miao, Shijie Cheng, Jia Xie
Summary: This study developed a design strategy of Sn-Cl dual doping to improve the ionic conductivity and lithium metal compatibility of Li6PS5I solid electrolytes. The optimal Li6.6P0.8Sn0.2S5I0.6Cl0.4 electrolyte exhibited ultrahigh conductivity (up to 0.96 mS/cm) and enhanced lithium metal compatibility. The assembled battery using LiNi0.6Mn0.2Co0.2O2 cathode and Li-In anode showed high initial discharge capacity (175.7 mAh/g at 0.1C) and maintained 79.2% after 100 cycles.
SCRIPTA MATERIALIA
(2023)
Article
Chemistry, Multidisciplinary
Mingsheng Qin, Ziqi Zeng, Xiaowei Liu, Yuanke Wu, Renjie He, Wei Zhong, Shijie Cheng, Jia Xie
Summary: This study successfully ameliorates graphite exfoliation-induced cell failure in propylene carbonate-based electrolyte by utilizing trifluoromethylbenzene as both electrolyte and surfactant, and constructing stable anion-induced solid electrolyte interphase at low concentration of lithium salt.
Article
Chemistry, Physical
Han Zhang, Ziqi Zeng, Shuping Wang, Yuanke Wu, Changhao Li, Mengchuang Liu, Xinlan Wang, Shijie Cheng, Jia Xie
Summary: A nonflammable diluted highly concentrated electrolyte has been developed to achieve high-voltage and safe lithium metal batteries. This electrolyte exhibits high thermal stability and reduces side reactions and stress crack between the electrolyte and battery materials.
Article
Chemistry, Multidisciplinary
Mengchuang Liu, Fenfen Ma, Zicheng Ge, Ziqi Zeng, Qiang Wu, Hui Yan, Yuanke Wu, Sheng Lei, Yanli Zhu, Shijie Cheng, Jia Xie
Summary: This article proposes a strategy for solving safety issues associated with flammable electrolytes in lithium-ion batteries by using non-flammable phosphate-based electrolytes. By using a specific combination of solvents, the interaction between lithium ions and phosphates is reduced, resulting in improved ion conductivity and lithium ion insertion.
SCIENCE CHINA-CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Tianyu Lei, Linfeng Peng, Cong Liao, Shuai Chen, Shijie Cheng, Jia Xie
Summary: In this study, the high conductivity Li5.5PS4.5Cl1.5 electrolyte was successfully obtained using lower milling speed and shorter annealing time, and it demonstrated stable cycling performance in an all-solid-state battery.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Xinlan Wang, Ziqi Zeng, Han Zhang, Mingsheng Qin, Yanli Zhu, Jia Xie
Summary: The introduction of 1,3,5-trifluorobenzene (F3B) as an additive for lithium-ion battery electrolytes can result in a solid electrolyte interface (SEI) rich in LiF. Compared to traditional fluorinated additives, F3B exhibits superior thermal stability and has a lower likelihood of generating hydrogen fluoride (HF) to damage the cathode.
CHEMICAL COMMUNICATIONS
(2023)
Review
Chemistry, Physical
Luwei Peng, Yang Zhang, Ruinan He, Nengneng Xu, Jinli Qiao
Summary: This article summarizes the development of electrocatalysts, the effect of the electrolyte, the progress in the development of the reactor, and the type of membrane in the CO2RR from industrial and commercial perspectives. The article points out that suitable design and development of the reactor are critical for efficient utilization of CO2 feedstock and cost reduction. Opportunities and challenges in the practical application of the CO2RR are also highlighted.
ACTA PHYSICO-CHIMICA SINICA
(2023)
