Metal exsolution engineering on perovskites for electrocatalysis: a perspective

Cation vacancy enriched nickel phosphide for efficient electrosynthesis of hydrogen peroxides

(2022) Zheng Zhou et al.   ADVANCED MATERIALS

Low‐Temperature Exsolution of Ni–Ru Bimetallic Nanoparticles from A‐Site Deficient Double Perovskites

(2022) Jia Guo et al.   Small

Manipulating Electrocatalytic Activity of Perovskite Oxide Through Electrochemical Treatment

(2022) Weiwei Fan et al.   Small

A Flexible Method to Fabricate Exsolution‐Based Nanoparticle‐Decorated Materials in Seconds

(2022) Zhu Sun et al.   Advanced Science

Controlling the Cation Exsolution of Perovskite to Customize Heterostructure Active Site for Oxygen Evolution Reaction

(2022) Yicheng Wei et al.   ACS Applied Materials & Interfaces

Synergistic interaction between in situ exsolved and phosphorized nanoparticles and perovskite oxides for enhanced electrochemical water splitting

(2022) Li Tan et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Anodic Shock-Triggered Exsolution of Metal Nanoparticles from Perovskite Oxide

(2022) Weiwei Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exsolution of CoFe(Ru) nanoparticles in Ru-doped (La0.8Sr0.2)0.9Co0.1Fe0.8Ru0.1O3−δ for efficient oxygen evolution reaction

(2022) Yi Liang et al.   Nano Research

2D/2D Black Phosphorus/Nickel Hydroxide Heterostructures for Promoting Oxygen Evolution via Electronic Structure Modulation and Surface Reconstruction

(2022) Jun Mei et al.   Advanced Energy Materials

A Highly Efficient Bifunctional Electrode Fashioned with In Situ Exsolved NiFe Alloys for Reversible Solid Oxide Cells

(2022) Junil Choi et al.   ACS Sustainable Chemistry & Engineering

Perovskite Oxides as Electrocatalysts for Hydrogen Evolution Reaction

(2022) Md. Sofiul Alom et al.   ACS Omega

Exsolution:A promising strategy for constructing advanced composite solids

(2022) Ruike Lv et al.   Materials Today Sustainability

In Situ Exsolution of Core‐Shell Structured NiFe/FeO x Nanoparticles on Pr 0.4 Sr 1.6 (NiFe) 1.5 Mo 0.5 O 6‐δ for CO 2 Electrolysis

(2022) Ting Tan et al.   ADVANCED FUNCTIONAL MATERIALS

The metal/oxide heterointerface delivered by solid-based exsolution strategy: A review

(2022) Yanling Yang et al.   CHEMICAL ENGINEERING JOURNAL

Boosting the stability of perovskites with exsolved nanoparticles by B-site supplement mechanism

(2022) Bo-Wen Zhang et al.   Nature Communications

Exceptionally durable CoFe-exsolved Sr0.95Nb0.1Co0.7Fe0.2O3–δ catalyst for rechargeable Zn–air batteries

(2022) Sangwoo Kim et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Ionic liquid-assisted exsolution of high-density Cu nanoparticles on La1.568Sr0.392Ce0.04NiCuxO4-δ as cathode for Zn-air batteries

(2022) Xu Ou et al.   CHEMICAL ENGINEERING JOURNAL

Trends and prospects of bimetallic exsolution

(2021) Chenyang Tang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Progress of Exsolved Metal Nanoparticles on Oxides as High Performance (Electro)Catalysts for the Conversion of Small Molecules

(2021) Xiang Sun et al.   Small

Perovskite Oxide Based Electrodes for the Oxygen Reduction and Evolution Reactions: The Underlying Mechanism

(2021) Casey E. Beall et al.   ACS Catalysis

Nanoparticle exsolution in perovskite oxide and its sustainable electrochemical energy systems

(2021) Quazi Arif Islam et al.   JOURNAL OF POWER SOURCES

Activation Strategies of Perovskite‐Type Structure for Applications in Oxygen‐Related Electrocatalysts

(2021) Yicheng Wei et al.   Small Methods

Tailoring Electrochemical Performance of Perovskite Anodes through In Situ Exsolution of Nanocatalysts

(2021) Zhu Sun et al.   ACS Applied Materials & Interfaces

Harnessing Selective Exsolution of Sn Metal to Enhance Electrical Conductivity in Oxygen‐Deficient Perovskite Stannates

(2021) Daseob Yoon et al.   ADVANCED FUNCTIONAL MATERIALS

Investigation of hetero-phases grown via in-situ exsolution on a Ni-doped (La,Sr)FeO3 cathode and the resultant activity enhancement in CO2 reduction

(2021) Dhruba J. Deka et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Facile fabrication of exsolved nanoparticle-decorated hollow ferrite fibers as active electrocatalyst for oxygen evolution reaction

(2021) Lei Fu et al.   CHEMICAL ENGINEERING JOURNAL

Structural Transformation of Heterogeneous Materials for Electrocatalytic Oxygen Evolution Reaction

(2021) Hui Ding et al.   CHEMICAL REVIEWS

Tuning Point Defects by Elastic Strain Modulates Nanoparticle Exsolution on Perovskite Oxides

(2021) Jiayue Wang et al.   CHEMISTRY OF MATERIALS

Recent development of perovskite oxide-based electrocatalysts and their applications in low to intermediate temperature electrochemical devices

(2021) Mengfei Zhang et al.   Materials Today

Development of Perovskite Oxide‐Based Electrocatalysts for Oxygen Evolution Reaction

(2021) Dong Liu et al.   Small

Controlling exsolution with a charge-balanced doping approach

(2021) Samuel A. Horlick et al.   Nano Energy

Exsolution Synthesis of Nanocomposite Perovskites with Tunable Electrical and Magnetic Properties

(2021) Jiayue Wang et al.   ADVANCED FUNCTIONAL MATERIALS

Surface‐Dependent Intermediate Adsorption Modulation on Iridium‐Modified Black Phosphorus Electrocatalysts for Efficient pH‐Universal Water Splitting

(2021) Jun Mei et al.   ADVANCED MATERIALS

Theoretical insights on the exsolved behavior of ruthenium atom in titanate perovskite

(2021) Zhongjie Lian et al.   APPLIED SURFACE SCIENCE

Bulk and surface exsolution produces a variety of Fe-rich and Fe-depleted ellipsoidal nanostructures in La0.6Sr0.4FeO3 thin films

(2021) Komal Syed et al.   Nanoscale

Promoting exsolution of RuFe alloy nanoparticles on Sr2Fe1.4Ru0.1Mo0.5O6−δ via repeated redox manipulations for CO2 electrolysis

(2021) Houfu Lv et al.   Nature Communications

Enhancing the Catalytic Activity and Coking Tolerance of the Perovskite Anode for Solid Oxide Fuel Cells through In Situ Exsolution of Co-Fe Nanoparticles

(2021) Haibo Hu et al.   ACS Catalysis

Unraveling the evolution of exsolved Fe–Ni alloy nanoparticles in Ni-doped La0.3Ca0.7Fe0.7Cr0.3O3−δ and their role in enhancing CO2–CO electrocatalysis

(2021) Haris Masood Ansari et al.   Journal of Materials Chemistry A

Layered-perovskite oxides with in situ exsolved Co–Fe alloy nanoparticles as highly efficient electrodes for high-temperature carbon dioxide electrolysis

(2021) Xiang Sun et al.   Journal of Materials Chemistry A

In situ construction of hetero-structured perovskite composites with exsolved Fe and Cu metallic nanoparticles as efficient CO2 reduction electrocatalysts for high performance solid oxide electrolysis cells

(2021) Xiuan Xi et al.   Journal of Materials Chemistry A

Lattice site–dependent metal leaching in perovskites toward a honeycomb-like water oxidation catalyst

(2021) Yubo Chen et al.   Science Advances

Phase engineering activation of low-cost iron-containing sulfide minerals for advanced electrocatalysis

(2021) Jun Mei et al.   JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY

In Situ Investigation of Reversible Exsolution/Dissolution of CoFe Alloy Nanoparticles in a Co‐Doped Sr 2 Fe 1.5 Mo 0.5 O 6− δ Cathode for CO 2 Electrolysis

(2020) Houfu Lv et al.   ADVANCED MATERIALS

In-situ growth of nanoparticles-decorated double perovskite electrode materials for symmetrical solid oxide cells

(2020) Bingbing Niu et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Replacement of Ca by Ni in a Perovskite Titanate to Yield a Novel Perovskite Exsolution Architecture for Oxygen‐Evolution Reactions

(2020) Jin Goo Lee et al.   Advanced Energy Materials

Exsolution of Cu nanoparticles in (LaSr)0.9Fe0.9Cu0.1O4 Ruddlesden-Popper oxide as symmetrical electrode for solid oxide cells

(2020) Lei Fu et al.   APPLIED SURFACE SCIENCE

Metal Nanoparticle Exsolution on a Perovskite Stannate Support with High Electrical Conductivity

(2020) Sangbae Yu et al.   NANO LETTERS

Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La 0.4 Sr 0.6 Co 0.2 Fe 0.7 Mo 0.1 O 3− δ with Efficient CO 2 Electrolysis

(2020) Houfu Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Exsolved Metal Nanoparticles: A Smart Approach for Optimization of Catalysts

(2020) Jiawei Zhang et al.   CHEMISTRY OF MATERIALS

In-situ exsolution of nanoparticles from Ni substituted Sr2Fe1.5Mo0.5O6 perovskite oxides with different Ni doping contents

(2020) Xinyang Meng et al.   ELECTROCHIMICA ACTA

Exsolved Alloy Nanoparticles Decorated Ruddlesden-Popper Perovskite as Sulfur-Tolerant Anodes for Solid Oxide Fuel Cells

(2020) Haidong Li et al.   ENERGY & FUELS

Infiltrated NiCo Alloy Nanoparticle Decorated Perovskite Oxide: A Highly Active, Stable, and Antisintering Anode for Direct‐Ammonia Solid Oxide Fuel Cells

(2020) Yufei Song et al.   Small

Mini-review of perovskite oxides as oxygen electrocatalysts for rechargeable zinc–air batteries

(2020) Yawen Dai et al.   CHEMICAL ENGINEERING JOURNAL

Understanding electrochemical switchability of perovskite-type exsolution catalysts

(2020) Alexander K. Opitz et al.   Nature Communications

Structural transformation of highly active metal–organic framework electrocatalysts during the oxygen evolution reaction

(2020) Shenlong Zhao et al.   Nature Energy

Highly active dry methane reforming catalysts with boosted in situ grown Ni-Fe nanoparticles on perovskite via atomic layer deposition

(2020) Sangwook Joo et al.   Science Advances

Enhancing the Bifunctional Catalytic Performance of Porous La0.9Mn0.6Ni0.4O3−δ Nanofibers for Li–O2 Batteries through Exsolution of Ni Nanoparticles

(2020) Shuai Guo et al.   ACS Applied Energy Materials

Nanoparticle Ex-solution for Supported Catalysts: Materials Design, Mechanism and Future Perspectives

(2020) Jun Hyuk Kim et al.   ACS Nano

Nano Polymorphism‐Enabled Redox Electrodes for Rechargeable Batteries

(2020) Jun Mei et al.   ADVANCED MATERIALS

Enhancing perovskite electrocatalysis through synergistic functionalization of B-site cation for efficient water splitting

(2020) Lina Tang et al.   CHEMICAL ENGINEERING JOURNAL

Efficient bifunctional electrocatalysts for solid oxide cells based on the structural evolution of perovskites with abundant defects and exsolved CoFe nanoparticles

(2020) Xiuan Xi et al.   JOURNAL OF POWER SOURCES

Non-aqueous solution synthesis of Pt-based nanostructures for fuel cell catalysts

(2020) Hualin Ding et al.   Materials Today Energy

A Highly Active and Redox-Stable SrGdNi0.2Mn0.8O4±δ Anode with in Situ Exsolution of Nanocatalysts

(2019) Kyeong Joon Kim et al.   ACS Catalysis

Cation-swapped homogeneous nanoparticles in perovskite oxides for high power density

(2019) Sangwook Joo et al.   Nature Communications

Electrical reduction of perovskite electrodes for accelerating exsolution of nanoparticles

(2019) Merika Chanthanumataporn et al.   ELECTROCHIMICA ACTA

High-Temperature CO2 Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects

(2019) Yuefeng Song et al.   ADVANCED MATERIALS

In situ exsolved Co nanoparticles on Ruddlesden-Popper material as highly active catalyst for CO2 electrolysis to CO

(2019) Seongmin Park et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Enhanced carbon dioxide electrolysis at redox manipulated interfaces

(2019) Wenyuan Wang et al.   Nature Communications

In Situ Observation of Nanoparticle Exsolution from Perovskite Oxides: From Atomic Scale Mechanistic Insight to Nanostructure Tailoring

(2019) Dragos Neagu et al.   ACS Nano

Exsolution and electrochemistry in perovskite solid oxide fuel cell anodes: Role of stoichiometry in Sr(Ti,Fe,Ni)O3

(2019) Tenglong Zhu et al.   JOURNAL OF POWER SOURCES

Toward Promising Cathode Catalysts for Nonlithium Metal–Oxygen Batteries

(2019) Jun Mei et al.   Advanced Energy Materials

Co-electrolysis of H2O and CO2 on exsolved Ni nanoparticles for efficient syngas generation at controllable H2/CO ratios

(2019) V. Kyriakou et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Symmetrical Exsolution of Rh Nanoparticles in Solid Oxide Cells for Efficient Syngas Production from Greenhouse Gases

(2019) Vasileios Kyriakou et al.   ACS Catalysis

Highly Efficient B-Site Exsolution Assisted by Co Doping in Lanthanum Ferrite toward High-Performance Electrocatalysts for Oxygen Evolution and Oxygen Reduction

(2019) Yilan Jiang et al.   ACS Sustainable Chemistry & Engineering

Enhancing oxygen reduction performance of oxide-CNT through in-situ generated nanoalloy bridging

(2019) Fengjiao Li et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Cogeneration of ethylene and energy in protonic fuel cell with an efficient and stable anode anchored with in-situ exsolved functional metal nanoparticles

(2018) Subiao Liu et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Operando X-ray spectroscopic tracking of self-reconstruction for anchored nanoparticles as high-performance electrocatalysts towards oxygen evolution

(2018) Sanzhao Song et al.   Energy & Environmental Science

Energetics of Nanoparticle Exsolution from Perovskite Oxides

(2018) Yang Gao et al.   Journal of Physical Chemistry Letters

Synergistically enhanced hydrogen evolution electrocatalysis by in situ exsolution of metallic nanoparticles on perovskites

(2018) Yinlong Zhu et al.   Journal of Materials Chemistry A

Electrocatalysis for the generation and consumption of fuels

(2018)   Nature Reviews Chemistry

Recent Advances in Zn-Ion Batteries

(2018) Ming Song et al.   ADVANCED FUNCTIONAL MATERIALS

Nanoscale Architecture of RuO2/La0.9Fe0.92Ru0.08–xO3−δ Composite via Manipulating the Exsolution of Low Ru-Substituted A-Site Deficient Perovskite

(2018) Yilan Jiang et al.   ACS Sustainable Chemistry & Engineering

Perovskites in catalysis and electrocatalysis

(2017) Jonathan Hwang et al.   SCIENCE

Exsolution trends and co-segregation aspects of self-grown catalyst nanoparticles in perovskites

(2017) Ohhun Kwon et al.   Nature Communications

Enhancing CO2 electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures

(2017) Lingting Ye et al.   Nature Communications

Self-Decorated MnO Nanoparticles on Double Perovskite Solid Oxide Fuel Cell Anode by in Situ Exsolution

(2017) Sivaprakash Sengodan et al.   ACS Sustainable Chemistry & Engineering

A rational design for enhanced oxygen reduction: Strongly coupled silver nanoparticles and engineered perovskite nanofibers

(2017) Ya-Qian Zhang et al.   Nano Energy

A coupling for success: Controlled growth of Co/CoO x nanoshoots on perovskite mesoporous nanofibres as high-performance trifunctional electrocatalysts in alkaline condition

(2017) Bin Hua et al.   Nano Energy

New Opportunity for in Situ Exsolution of Metallic Nanoparticles on Perovskite Parent

(2016) Yi-Fei Sun et al.   NANO LETTERS

Switching on electrocatalytic activity in solid oxide cells

(2016) Jae-ha Myung et al.   NATURE

Bifunctional Catalyst of Core–Shell Nanoparticles Socketed on Oxygen-Deficient Layered Perovskite for Soot Combustion: In Situ Observation of Synergistic Dual Active Sites

(2016) Yi-Fei Sun et al.   ACS Catalysis

Exsolved Fe–Ni nano-particles from Sr2Fe1.3Ni0.2Mo0.5O6 perovskite oxide as a cathode for solid oxide steam electrolysis cells

(2016) Y. Wang et al.   Journal of Materials Chemistry A

CO2-to-CO conversion on layered perovskite with in situ exsolved Co–Fe alloy nanoparticles: an active and stable cathode for solid oxide electrolysis cells

(2016) Subiao Liu et al.   Journal of Materials Chemistry A

From material design to mechanism study: Nanoscale Ni exsolution on a highly active A-site deficient anode material for solid oxide fuel cells

(2016) Yang Gao et al.   Nano Energy

Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers

(2016) John T. S. Irvine et al.   Nature Energy

Computational predictions of energy materials using density functional theory

(2016) Anubhav Jain et al.   Nature Reviews Materials

Exsolution of Fe and SrO Nanorods and Nanoparticles from Lanthanum Strontium Ferrite La0.6Sr0.4FeO3−δ Materials by Hydrogen Reduction

(2015) Ramona Thalinger et al.   Journal of Physical Chemistry C

Evidence and Model for Strain-Driven Release of Metal Nanocatalysts from Perovskites during Exsolution

(2015) Tae-Sik Oh et al.   Journal of Physical Chemistry Letters

Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution

(2015) Dragos Neagu et al.   Nature Communications

Double-Layered Perovskite Anode with in Situ Exsolution of a Co–Fe Alloy To Cogenerate Ethylene and Electricity in a Proton-Conducting Ethane Fuel Cell

(2015) Subiao Liu et al.   ACS Catalysis

In situ growth of nanoparticles through control of non-stoichiometry

(2013) Dragos Neagu et al.   Nature Chemistry

Step-change in high temperature steam electrolysis performance of perovskite oxide cathodes with exsolution of B-site dopants

(2012) George Tsekouras et al.   Energy & Environmental Science

Unveiling Structure–Property Relationships in Sr2Fe1.5Mo0.5O6−δ, an Electrode Material for Symmetric Solid Oxide Fuel Cells

(2012) Ana B. Muñoz-García et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles

(2011) J. Suntivich et al.   SCIENCE

A Co–Fe alloy as alternative anode for solid oxide fuel cell

(2008) Z.G. Lu et al.   JOURNAL OF POWER SOURCES