Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 310, Issue 1, Pages 279-285Publisher
SPRINGER
DOI: 10.1007/s10967-016-4821-6
Keywords
Carbon nanofibers; Sr(II); Adsorption mechanism; Surface complexation modeling
Funding
- Shaoxing University [20155029]
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Effect of water chemistry on Sr(II) adsorption onto carbon nanofibers (CNFs) was investigated by batch and modeling techniques. The characterization results showed that CNFs comprised a variety of functional groups such as -OH and -COOH groups. No effect of ionic strength indicated that Sr(II) adsorption onto CNFs was the inner-sphere surface complexation. The maximum adsorption capacity of CNFs was 58.72 mg/g at pH 4.5 and 293 K. The thermodynamic parameters suggested that Sr(II) adsorption was an endothermic and spontaneous processes. Diffuse layer model can give an excellent fits with SOSr+ and (SO)(2)Sr(OH) (2) (2-) inner-sphere surface complexes.
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