4.8 Article

Remarkable performance improvement of inexpensive ball-milled Si nanoparticles by carbon-coating for Li-ion batteries

Journal

JOURNAL OF POWER SOURCES
Volume 319, Issue -, Pages 99-103

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2016.04.050

Keywords

Si/C composites; Si anodes; LIBs; Structure change; Transmission electron microscopy

Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology
  2. [2206]
  3. [25107705]

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Si nanoparticles prepared by ball-milling (BM-Si) are expected as practical negative-electrode materials for lithium-ion batteries, but their performance is much lower than those of more expensive Si nano materials, such as chemical-vapor-deposition derived Si nanoparticles (CVD-Si) having a tight network structure. It is found that carbon-coating of aggregations of BM-Si forms a quasi-network structure, thereby making the performance comparable to that of CVD-Si under capacity restriction (to 1500 mAh g(-1)). In this case, the structural transition of BM-Si during charge/discharge cycling is characterized by the formation of a specific 'wrinkled structure', which is very similar to that formed in CVD-Si. (C) 2016 Elsevier B.V. All rights reserved.

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