Review
Chemistry, Physical
Huijun Lin, Jingya Yu, Feiyang Chen, Renjie Li, Bao Yu Xia, Zheng-Long Xu
Summary: This paper summarizes the state-of-the-art advances in understanding the interphases for multivalent metal anodes revealed by transmission electron microscopy (TEM) methods. The dynamic visualization of the vulnerable chemical structures in interphase layers has been achieved through operando and cryogenic TEM with high spatial and temporal resolutions. The features and influencing factors of the interphases on different metal anodes are elucidated, and perspectives for further research and regulation of interphases for practical MMBs are proposed.
Article
Nanoscience & Nanotechnology
Saran Pidaparthy, Mei Luo, Marco-Tulio F. Rodrigues, Jian-Min Zuo, Daniel P. Abraham
Summary: This study reveals the heterogeneous physicochemical evolution of silicon anodes in lithium-ion cells, and its correlation with capacity fade. It is found that silicon particles near the anode surface react differently from those near the copper current collector. Material and cell designs are needed to minimize electrode expansion and enhance anode homogeneity.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Xiaoyu Li, Wei Zhang
Summary: SiCf/C/TiAl matrix composite is a high temperature structural material with potential wide applications, capable of replacing traditional high temperature alloys in aerospace. The study found that different reaction products are formed under specific temperature and pressure conditions, with Ti5Si3 being the final product at certain parameters.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2021)
Article
Materials Science, Multidisciplinary
H. Plaisantin, S. Jacques, J. Danet, G. Camus, H. Delpouve
Summary: The BN interphases synthesized by CVI at 900 and 1200 degrees C exhibit varying degrees of crystallization and microstructure, affecting the growth of the SiC matrix in different ways.
MATERIALS CHARACTERIZATION
(2021)
Article
Chemistry, Multidisciplinary
Anastasiia N. Petrova, Dmitry Y. Rasposienko, Irina G. Brodova, Liudmila A. Yolshina, Roman V. Muradymov, Artem A. Markin, Vyacheslav V. Marchenkov, Bogdan M. Fominykh
Summary: In this study, severe plastic deformation was applied to Al-Fe composites reinforced with graphene sheets using high-pressure torsion. The results revealed the dissolution of iron-containing aluminides and the formation of a submicrocrystalline structure. Furthermore, the hardness and electrical properties of the graphene composites showed differences compared to the matrix alloy.
APPLIED SCIENCES-BASEL
(2023)
Review
Chemistry, Physical
Azira Khairudin, Syahida Suhaimi, Nur Athirah Mohd Taib, Mohd Ikmar Nizam Mohamad Isa, Wan Zakiah Wan Ismail
Summary: This review provides a comprehensive overview of the research progress on ZnO/C composites in lithium-ion batteries in the past 5 years. The effects of different carbonaceous materials on the performance of binary and ternary ZnO/C composites are analyzed and compared.
Article
Chemistry, Physical
Andriy Lotnyk, Isom Hilmi, Mario Behrens, Bernd Rauschenbach
Summary: Interfacial phase change memory based on chalcogenide-based superlattices shows promising device performance as an alternative to conventional phase change memory. Experimental results reveal the thermodynamically driven formation of layered Ge-Sb-Te crystal structures at high growing temperatures, while the diffusivity of Ge and Sb atoms can be restricted at low deposition temperatures, offering a pathway to optimize the microstructure of superlattices.
APPLIED SURFACE SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
Irina Brodova, Liudmila Yolshina, Sergey Razorenov, Dmitriy Rasposienko, Anastasia Petrova, Irina Shirinkina, Evgeny Shorokhov, Roman Muradymov, Gennady Garkushin, Andrey Savinykh
Summary: This study investigates the structure and mechanical properties of composites consisting of a metal matrix based on aluminum and its alloys and graphene synthesized in situ. It was found that grain refinement increases the hardness of the composites, and decreasing the grain size improves the elastic-plastic properties. The reinforcing effect of graphene is also influenced by the grain size of the matrix.
Article
Materials Science, Multidisciplinary
B. D. S. Deeraj, Gejo George, N. R. Dhineshbabu, Suryasarathi Bose, Kuruvilla Joseph
Summary: This study focused on the preparation and characterization of zirconia incorporated PAN-based carbon nanofiber reinforced epoxy composites as effective EMI shielding materials. The results showed superior storage modulus and excellent EMI shielding effectiveness, especially stacking the ZrO2@CNF mats to achieve outstanding shielding effectiveness above -90 dB in the Ku band, which is significant for industrial, radar, and military applications.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Chemistry, Physical
David Reyes, Virgil Malard, Stefan Drawin, Alain Couret, Jean-Philippe Monchoux
Summary: The deformation mechanisms of an Nb-20Si-25Ti-6Al-3Cr-3Mo alloy deformed in compression at 1000 degrees C were studied, showing that only the Nbss matrix exhibited plastic deformation at this temperature. Interactions between delta-Nb11Si4 precipitates and dislocations were observed.
Article
Chemistry, Physical
Jin-Hu Dou, Maxx Q. Arguilla, Yi Luo, Jian Li, Weizhe Zhang, Lei Sun, Jenna L. Mancuso, Luming Yang, Tianyang Chen, Lucas R. Parent, Grigorii Skorupskii, Nicole J. Libretto, Chenyue Sun, Min Chieh Yang, Phat Vinh Dip, Edward J. Brignole, Jeffrey T. Miller, Jing Kong, Christopher H. Hendon, Junliang Sun, Mircea Dinca
Summary: Researchers have successfully grown single crystals of 2D metal-organic frameworks up to 200 µm in size by balancing in-plane and out-of-plane interactions, revealing anisotropic transport and a clear correlation between conductivity and the nature of the metal cation in the sheets.
Article
Materials Science, Multidisciplinary
Laura Silvestroni, Simone Failla, Nicola Gilli, Cesare Melandri, Umut Savac, Servet Turan, Diletta Sciti
Summary: This study investigates the microstructural features of B4C-TiB2 composites and their evolution from powder processing to sintering. Nanoindentation was used to correlate small-scale grain structures to local properties, providing insights into mechanical behavior. The development of a core/shell structure with different compositions and variable guest cations in the boride grains was observed in dense ceramics, revealing new findings for the synthesis of high-performance materials.
MATERIALS & DESIGN
(2021)
Article
Chemistry, Multidisciplinary
Bela Pecz, Nikolaos Vouroutzis, Gyorgy Zoltan Radnoczi, Nikolaos Frangis, John Stoemenos
Summary: Si whiskers grown by Ni-Metal-Induced-Lateral-Crystallization (Ni-MILC) at 413 degrees C have different characteristics compared to those grown by the Vapor Liquid Solid (VLS) method, including crystalline quality and cross-section shape. While both methods face contamination issues, the Ni-MILC grown Si whiskers are more compatible with current CMOS processes.
Review
Chemistry, Multidisciplinary
Haofei Zhao, Yuchen Zhu, Huanyu Ye, Yang He, Hao Li, Yifei Sun, Feng Yang, Rongming Wang
Summary: Nanocrystals play a crucial role in material sciences and industry. Designing nanocrystals with desired structures and properties is a major challenge that requires a deep understanding of atomic-scale dynamics. In situ transmission electron microscopy (TEM), especially environmental TEM, has provided valuable insights into nanocrystals. This comprehensive review highlights the progress in the understanding of nanocrystal dynamics, including nucleation and growth, structure evolution, and dynamics in reaction conditions.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
M. A. Mazo, A. C. Caballero, J. Rubio
Summary: In this study, cheap, abundant, and easily-obtained carbon fillers such as graphite and carbon black were successfully incorporated into a silicon oxycarbide matrix to obtain dense crack-free bulk composites with enhanced electrical and thermal conductivities. Raman parameters were crucial for understanding the electronic and/or phonon transport in the composites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Review
Chemistry, Multidisciplinary
Takeharu Yoshii, Koki Chida, Hirotomo Nishihara, Fumito Tani
Summary: Ordered carbonaceous frameworks (OCFs) are a new class of carbon materials with a three-dimensional ordered structure, high electrical conductivity, thermal/chemical stability, and mechanical flexibility, suitable for various applications. This feature article summarizes the synthetic strategies and characteristics of OCFs in comparison with conventional organic-based frameworks and porous carbons, to discuss their potential applications and further development.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Jun Maruyama, Shohei Maruyama, Yukiyasu Kashiwagi, Mitsuru Watanabe, Tsutomu Shinagawa, Toru Nagaoka, Toshiyuki Tamai, Naoya Ryu, Koichi Matsuo, Mao Ohwada, Koki Chida, Takeharu Yoshii, Hirotomo Nishihara, Fumito Tani, Hiroshi Uyama
Summary: While the functions of carbon materials with precisely controlled nanostructures have been reported, their chiral discriminating abilities have not been explored. In this study, chiral discrimination is achieved using helical carbon materials devoid of chiral attachments, and the mechanisms are confirmed through various experiments.
Article
Chemistry, Multidisciplinary
Masanori Yamamoto, Qi Zhao, Shunsuke Goto, Yu Gu, Takaaki Toriyama, Tomokazu Yamamoto, Hirotomo Nishihara, Alex Aziz, Rachel Crespo-Otero, Devis Di Tommaso, Masazumi Tamura, Keiichi Tomishige, Takashi Kyotani, Kaoru Yamazaki
Summary: gamma-Al2O3 nanoparticles promote the pyrolytic carbon deposition of CH4, resulting in the formation of single-walled nanoporous graphene (NPG) without the need for transition metals. This study investigates the early-stage CH4 activation on gamma-Al2O3 nanoparticles for NPG formation, highlighting the importance of oxygen vacancies for promoting NPG growth. The findings provide insights for the precise control of oxygen vacancies in carbon growth.
Article
Chemistry, Physical
Atsushi Gabe, Akira Takatsuki, Masahiko Hiratani, Masato Kaneeda, Yoshiaki Kurihara, Takayuki Aoki, Hiroki Mashima, Takafumi Ishii, Jun-ichi Ozaki, Hirotomo Nishihara, Takashi Kyotani
Summary: This study demonstrates that oxidized carbon blacks can serve as efficient catalysts for the hydrolysis of cellulose, with two types of acidic oxygen-containing functional groups (carboxyl groups and phenol groups) on the external surface exhibiting almost equal catalytic activity towards cellulose molecules.
Article
Nanoscience & Nanotechnology
Tracy T. Chuong, Toshihiko Ogura, Norihito Hiyoshi, Kazuma Takahashi, Sangho Lee, Keita Hiraga, Hiroki Iwase, Akira Yamaguchi, Kiyoto Kamagata, Eriko Mano, Satoshi Hamakawa, Hirotomo Nishihara, Takashi Kyotani, Galen D. Stucky, Tetsuji Itoh
Summary: This study introduces synthesized giant carbon nano-test tubes (GCNTTs) as radiation-insulating materials to improve sample preparation and imaging conditions for cryogenic electron microscopy. High-resolution images of proteins, such as hemoglobin and D-fructose dehydrogenase, were successfully obtained using GCNTTs, which also protected the proteins from radiation-induced denaturation.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Chemistry, Multidisciplinary
Zheng-Ze Pan, Wei Lv, Quan-Hong Yang, Hirotomo Nishihara
Summary: The ice-templating approach is a popular method for preparing macroporous monoliths, offering environmental friendliness and low cost. Through a directional freezing process, aligned ice crystals are formed, resulting in a new material genre called aligned macroporous monoliths (AMMs). This review provides an overview of the IT technique and the preparation of AMMs, focusing on two representative AMMs: aligned micro-honeycomb monoliths and aligned microlamellar monoliths. The structural anisotropy and regularity of these AMMs make them suitable for various applications, such as thermal insulation, filtration, energy storage, and structural engineering. The future directions in this research field are also discussed.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
(2022)
Article
Chemistry, Multidisciplinary
Zhijia Huang, Zhiyuan Han, Baozheng Jiang, Yunbo Zhang, Sichen Gu, Chen Zhang, Zhengze Pan, Hirotomo Nishihara, Quan-Hong Yang, Wei Lv
Summary: The paper proposes a dense Li-ion flux regulating layer on the separator to suppress the dendrite growth of Li metal anode, leading to a potential application in next-generation Li metal batteries.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Kenichi Kato, Nobuyoshi Seto, Koki Chida, Takeharu Yoshii, Motohiro Mizuno, Hirotomo Nishihara, Shunsuke Ohtani, Tomoki Ogoshi
Summary: This study reports a new method for the preparation of hexa-aminated trinaphtho[3.3.3]propellane and demonstrates its high activity towards condensation reactions with boronic acids and aldehydes. The resulting amorphous polymeric solid exhibits excellent adsorption capacity for hydrocarbon gases and vapors.
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
(2022)
Article
Chemistry, Physical
Koki Chida, Takeharu Yoshii, Norihito Hiyoshi, Tetsuji Itoh, Jun Maruyama, Kazuhide Kamiya, Masataka Inoue, Fumito Tani, Hirotomo Nishihara
Summary: Ordered carbonaceous frameworks (OCFs) are unique carbon alloys that combine the advantages of organic-based nanoporous frameworks and carbon materials. This study demonstrates the synthesis of OCFs with single-atomic Co and Cu sites, which show developed microporosity and electrochemical activity, as well as a synergistic effect between Co and Cu.
Article
Chemistry, Physical
Jittraporn Saengkaew, Takashi Kameda, Manai Ono, Emiko Mizuki, Shintaroh Nagaishi, Shinichiroh Iwamura, Shin R. Mukai, Shoichi Matsuda
Summary: Lithium-oxygen batteries (LOBs) are a promising option for rechargeable batteries with high theoretical energy densities. The optimization of the carbon-based positive electrode is crucial for the practical implementation of LOB technologies. In this study, carbon gel-based self-standing membranes were prepared as positive electrodes and their performances in LOBs were evaluated under lean-electrolyte, high-areal-capacity conditions. The results indicated that nanometer-sized pores had limited effects on cycle performance but contributed to enhancing discharge capacity; macro-sized pores had a positive effect on enhancing discharge capacity; crystallinity and surface functional groups influenced discharge potential and cycle life. This study highlights the importance of controlling the physicochemical properties of porous carbon-based positive electrodes for achieving LOBs with high energy densities and extended cycle lives.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Physical
Shintaroh Nagaishi, Shinichiroh Iwamura, Takafumi Ishii, Shin R. Mukai
Summary: Controlling the characteristics of Li2O2 deposition during discharging in lithium-air batteries (LABs) can reduce the overpotential required for charging, therefore improving the cycle performance of LABs. The presence of functional groups in the cathode carbon affects the deposition of Li2O2 and the performance of LABs. By increasing the number of oxygen-containing functional groups (OCFGs) in carbon gels, the deposition of Li2O2 within the mesopores of carbon particles can be increased, leading to a reduction in charging overpotential. However, a large number of OCFGs can cause side reactions that deteriorate cycle performance, which can be mitigated by heat treatment.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Physical
Shintaroh Nagaishi, Shinichiroh Iwamura, Takafumi Ishii, Shin R. Mukai
Summary: In this study, the effects of functional groups in the cathode carbon on the characteristics of Li2O2 and the performance of lithium-air batteries were investigated. It was found that increasing the number of oxygen-containing functional groups (OCFGs) through acid treatment can increase the deposition of Li2O2 within the mesopores of carbon particles, leading to a reduction in charging overpotential. However, CGs with a large number of OCFGs tend to undergo side reactions that deteriorate cycle performance, which can be mitigated by removing carboxyl groups through heat treatment.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Meeting Abstract
Chemistry, Physical
Hirotomo Nishihara, Hong-Wei Zhao, Kazuya Kanamaru, Keita Nomura, Mao Ohwada, Masashi Ito, Li-Xiang Li, Bai-Gang An, Toshihide Horikawa, Takashi Kyotani
Article
Chemistry, Physical
Qi Zhao, Masanori Yamamoto, Kaoru Yamazaki, Hirotomo Nishihara, Rachel Crespo-Otero, Devis Di Tommaso
Summary: Chemical vapor deposition of methane onto alumina nanoparticles is an important method for synthesizing graphene meso-sponge. The initial stages of graphene growth on alumina surfaces were studied using density functional theory calculations. The mechanism of methane dissociation and the formation of reactive intermediates were modeled. The study provides insights into the catalytic activity and growth behavior of graphene on alumina surfaces.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Hirotomo Nishihara, Akio Harigaya, Alberto Castro-Muniz, Mao Ohwada, Takashi Kyotani, Yuta Nishina
Summary: Microporous polymers with exposed C-60 surfaces have been synthesized by a new esterification pathway, exhibiting a high specific surface area and enhanced hydrogen spillover.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)