4.8 Article

High-performance aqueous asymmetric supercapacitor based on K0.3WO3 nanorods and nitrogen-doped porous carbon

Journal

JOURNAL OF POWER SOURCES
Volume 330, Issue -, Pages 219-230

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2016.09.022

Keywords

Supercapacitor; Tungstate; Biomass carbon; Electrodes

Funding

  1. National Science Foundation of China [51462032]
  2. program for Changjiang Scholars and Innovative Research Team in University [IRT15R56]
  3. Science and Technology Program of Gansu Province [1606RJIA324]
  4. China Postdoctoral Science Foundation [2013M540778]
  5. Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education
  6. Key Laboratory of Polymer Materials of Gansu Province

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A novel asymmetric supercapacitor device for energy storage is fabricated using K0.3WO3 nanorods as negative electrode and nitrogen-doped porous carbon (CBC-1) based on agricultural wastes corn bract as positive electrode. The K0.3WO3 nanorods are composed of some thinner needle-shaped nanorods which are parallel to each other, and the CBC-1 reveals rough surface of coral-like frameworks with abundant nanopores. The structures can provide high surface area, low diffusion paths and intercalation/de-intercalation of electrolyte ions between the electrode/electrolyte interfaces. Thus, the asymmetric supercapacitor exhibits high energy density about 26.3 Wh kg(-1) at power density of 404.2 W kg(-1) in the wide voltage region of 0-1.6 V, as well as a good electrochemical stability (80% capacitance retention after 1000 cycles). Such outstanding electrochemical behaviors imply the CBC-1//K0.3WO3 asymmetric supercapacitor is a promising practical energy-storage system. (C) 2016 Elsevier B.V. All rights reserved.

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