Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 20, Issue 8-11, Pages 1016-1024Publisher
WORLD SCI PUBL CO INC
DOI: 10.1142/S108842461650070X
Keywords
BODIPY; singlet oxygen; XPS spectroscopy; TD-DFT calculations; APDT
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Funding
- Department of Science and Technology (DST)
- National Research Foundation (NRF) of South Africa through DST/NRF South African Research Chairs Initiative
- CSUR grant from NRF of South Africa [UID 93627]
- Rhodes University
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A series of boron dipyrromethene (BODIPY) dyes with properties that are ideal for a good photosensitizer have been prepared. Functionalization with bromine atoms and attachment to gold nanoparticles through a meso-aniline group results in high singlet oxygen quantum yields and low fluorescent quantum yields. Molecular modelling was used to analyze trends in the MO energies of various brominated aniline BODIPY dyes.
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