End-Tethered Chains Increase the Local Glass Transition Temperature of Matrix Chains by 45 K Next to Solid Substrates Independent of Chain Length
Published 2022 View Full Article
- Home
- Publications
- Publication Search
- Publication Details
Title
End-Tethered Chains Increase the Local Glass Transition Temperature of Matrix Chains by 45 K Next to Solid Substrates Independent of Chain Length
Authors
Keywords
-
Journal
ACS Macro Letters
Volume 12, Issue 1, Pages 1-7
Publisher
American Chemical Society (ACS)
Online
2022-12-15
DOI
10.1021/acsmacrolett.2c00582
References
Ask authors/readers for more resources
Related references
Note: Only part of the references are listed.- Influence of Attractive Functional Groups on the Segmental Dynamics and Glass Transition in Associating Polymers
- (2022) Ashesh Ghosh et al. MACROMOLECULES
- Structural Relaxation and Vitrification in Dense Cross-Linked Polymer Networks: Simulation, Theory, and Experiment
- (2022) Baicheng Mei et al. MACROMOLECULES
- Cooperative Intramolecular Dynamics Control the Chain-Length-Dependent Glass Transition in Polymers
- (2022) Daniel L. Baker et al. Physical Review X
- Utilization of Polymer-Tethered Probes for the Assessment of Segmental Polymer Dynamics near the Glass Transition
- (2022) Hyangseok Lee et al. MACROMOLECULES
- Polymer segmental dynamics near the interface of silica particles in the particle/polymer composites
- (2022) Ganghee Park et al. JOURNAL OF COLLOID AND INTERFACE SCIENCE
- Direct Observations of Segmental Dynamics at the Polymer–Substrate Interface Enabled by Localizing Fluorescent Probes with Polymer Brushes
- (2021) Yura Chung et al. MACROMOLECULES
- Gradient in refractive index reveals denser near free surface region in thin polymer films
- (2021) Yixuan Han et al. JOURNAL OF CHEMICAL PHYSICS
- Glass transition temperature of single-chain polystyrene particles end-grafted to oxide-coated silicon
- (2020) Yawei Li et al. JOURNAL OF CHEMICAL PHYSICS
- Thermal and Rheological Analysis of Polystyrene-Grafted Silica Nanocomposites
- (2020) Nazam Sakib et al. MACROMOLECULES
- Microscopic Theory of the Effect of Caging and Physical Bonding on Segmental Relaxation in Associating Copolymer Liquids
- (2020) Ashesh Ghosh et al. MACROMOLECULES
- Theory of Spatial Gradients of Relaxation, Vitrification Temperature and Fragility of Glass-Forming Polymer Liquids Near Solid Substrates
- (2020) Anh D. Phan et al. ACS Macro Letters
- Experimental study of substrate roughness on the local glass transition of polystyrene
- (2020) Xinru Huang et al. JOURNAL OF CHEMICAL PHYSICS
- Comparing refractive index and density changes with decreasing film thickness in thin supported films across different polymers
- (2020) Yixuan Han et al. JOURNAL OF CHEMICAL PHYSICS
- Molecular Weight Dependence of the Glass Transition Temperature (Tg)-Confinement Effect in Well-Dispersed Poly(2-vinyl pyridine)–Silica Nanocomposites: Comparison of Interfacial Layer Tg and Matrix Tg
- (2020) Tong Wei et al. MACROMOLECULES
- The interfacial zone in thin polymer films and around nanoparticles in polymer nanocomposites
- (2019) Wengang Zhang et al. JOURNAL OF CHEMICAL PHYSICS
- How Tethered Probes Report the Dynamics of a Polymer near the Glass Transition
- (2019) Jiwon Choi et al. ACS Macro Letters
- Progress towards a phenomenological picture and theoretical understanding of glassy dynamics and vitrification near interfaces and under nanoconfinement
- (2019) Kenneth S. Schweizer et al. JOURNAL OF CHEMICAL PHYSICS
- Theory of activated glassy dynamics in randomly pinned fluids
- (2018) Anh D. Phan et al. JOURNAL OF CHEMICAL PHYSICS
- Nonmonotonic Glass Transition Temperature of Polymer Films Supported on Polymer Brushes
- (2018) Hoyeon Lee et al. MACROMOLECULES
- Why we need to look beyond the glass transition temperature to characterize the dynamics of thin supported polymer films
- (2018) Wengang Zhang et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- Optimizing the Grafting Density of Tethered Chains to Alter the Local Glass Transition Temperature of Polystyrene near Silica Substrates: The Advantage of Mushrooms over Brushes
- (2018) Xinru Huang et al. ACS Macro Letters
- Influence of grafting on the glass transition temperature of PS thin films
- (2017) Marceau Hénot et al. EUROPEAN PHYSICAL JOURNAL E
- Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids
- (2017) Sanat K. Kumar et al. JOURNAL OF CHEMICAL PHYSICS
- The relationship between dynamic and pseudo-thermodynamic measures of the glass transition temperature in nanostructured materials
- (2017) Jayachandra Hari Mangalara et al. JOURNAL OF CHEMICAL PHYSICS
- Local glass transition temperature Tg(z) of polystyrene next to different polymers: Hard vs. soft confinement
- (2017) Roman R. Baglay et al. JOURNAL OF CHEMICAL PHYSICS
- Polystyrene-Grafted Silica Nanoparticles: Investigating the Molecular Weight Dependence of Glass Transition and Fragility Behavior
- (2017) Shadid Askar et al. MACROMOLECULES
- 50th Anniversary Perspective: Are Polymer Nanocomposites Practical for Applications?
- (2017) Sanat K. Kumar et al. MACROMOLECULES
- Grafting density dominant glass transition of dry polystyrene brushes
- (2017) Biao Zuo et al. Soft Matter
- Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites
- (2016) Adam P. Holt et al. ACS Nano
- Communication: Experimentally determined profile of local glass transition temperature across a glassy-rubbery polymer interface with a Tg difference of 80 K
- (2015) Roman R. Baglay et al. JOURNAL OF CHEMICAL PHYSICS
- A unifying framework to quantify the effects of substrate interactions, stiffness, and roughness on the dynamics of thin supported polymer films
- (2015) Paul Z. Hanakata et al. JOURNAL OF CHEMICAL PHYSICS
- A coarse-grained molecular dynamics study of segmental structure and mobility in capped crosslinked copolymer films
- (2015) T. Davris et al. JOURNAL OF CHEMICAL PHYSICS
- On the equivalence between the thermodynamic and dynamic measurements of the glass transition in confined polymers
- (2015) Rodney D. Priestley et al. JOURNAL OF NON-CRYSTALLINE SOLIDS
- Glass Formation near Covalently Grafted Interfaces: Ionomers as a Model Case
- (2015) Dihui Ruan et al. MACROMOLECULES
- Dynamical Theory of Segmental Relaxation and Emergent Elasticity in Supercooled Polymer Melts
- (2015) Stephen Mirigian et al. MACROMOLECULES
- Substantial spatial heterogeneity and tunability of glass transition temperature observed with dense polymer brushes prepared by ARGET ATRP
- (2015) Tian Lan et al. POLYMER
- Interfacial mobility scale determines the scale of collective motion and relaxation rate in polymer films
- (2014) Paul Z. Hanakata et al. Nature Communications
- Nanocomposites with Polymer Grafted Nanoparticles
- (2013) Sanat K. Kumar et al. MACROMOLECULES
- Effect of Adjacent Rubbery Layers on the Physical Aging of Glassy Polymers
- (2013) Phillip M. Rauscher et al. MACROMOLECULES
- Quantitative Analysis of Interdigitation Kinetics between a Polymer Melt and a Polymer Brush
- (2013) Alexis Chennevière et al. MACROMOLECULES
- Theory and simulation studies of effective interactions, phase behavior and morphology in polymer nanocomposites
- (2013) Venkat Ganesan et al. Soft Matter
- Mechanical Properties of Thin Glassy Polymer Films Filled with Spherical Polymer-Grafted Nanoparticles
- (2012) Damien Maillard et al. NANO LETTERS
- Static point-to-set correlations in glass-forming liquids
- (2012) Ludovic Berthier et al. PHYSICAL REVIEW E
- Glass-Transition Temperature Gradient in Nanocomposites: Evidence from Nuclear Magnetic Resonance and Differential Scanning Calorimetry
- (2012) Aurélie Papon et al. PHYSICAL REVIEW LETTERS
- Ideal glass transitions by random pinning
- (2012) C. Cammarota et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- Glass Transition Temperature of Polymer Films That Slip
- (2011) Andrew Clough et al. MACROMOLECULES
- Glass Transition Behavior of PS Films on Grafted PS Substrates
- (2010) Hoyeon Lee et al. MACROMOLECULES
- Segmental Dynamics in PMMA-Grafted Nanoparticle Composites
- (2010) Pinar Akcora et al. MACROMOLECULES
- Confinement effects on glass transition temperature, transition breadth, and expansivity: Comparison of ellipsometry and fluorescence measurements on polystyrene films
- (2009) S. Kim et al. EUROPEAN PHYSICAL JOURNAL E
- Polymer chain dynamics and glass transition in athermal polymer/nanoparticle mixtures
- (2009) Hyunjoon Oh et al. NATURE MATERIALS
- Relation between Glass Transition Temperatures in Polymer Nanocomposites and Polymer Thin Films
- (2008) Jamie M. Kropka et al. PHYSICAL REVIEW LETTERS
- Adhesion mechanisms at soft polymer interfaces
- (2007) L. Leger et al. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES
Add your recorded webinar
Do you already have a recorded webinar? Grow your audience and get more views by easily listing your recording on Peeref.
Upload NowAsk a Question. Answer a Question.
Quickly pose questions to the entire community. Debate answers and get clarity on the most important issues facing researchers.
Get Started