4.6 Article

Large-Scale Uniform Two-Dimensional Hexagonal Arrays of Gold Nanoparticles Templated from Mesoporous Silica Film for Surface-Enhanced Raman Spectroscopy

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 120, Issue 42, Pages 24382-24388

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.6b08116

Keywords

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Funding

  1. MOST (Ministry of Science and Technology), Taiwan

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A good surface-enhanced Raman spectroscopy (SERS) substrate requires precise control of the enhancement factor in large area which may be achieved with large-scale hot spot engineering. Here, we present a facile method for synthesizing 2-D hexagonally patterned gold nanoparticle arrays on centimeter-sized substrates of mesoporous silica thin films with vertical nano channels by chemical reduction. Scanning electron microscopy images showed densely packed gold nanoparticles directly anchored on the openings of vertical mesopores (similar to 5 nm) leading to 2 nm nanogaps between the gold nanoparticles. The gold nanoparticle arrays showed red-shifted localized surface plasmon resonance spectra due to strong couplings between close-packed gold. The dense on-substrate 2 nm plasmonic nanogaps lead to highly enhanced local electric field and excellent macroscopic uniformity in SERS.

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