4.6 Article

Photoelectrocatalytic reduction of perchlorate in aqueous solutions over Ag doped TiO2 nanotube arrays

Journal

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2016.05.023

Keywords

Perchlorate; Photoelectrocatalytic reduction; TiO2 nanotube arrays; Ag nanoparticles

Funding

  1. State Key Laboratory of Urban Water Resource and Environment of Harbin Institute of Technology [2016DX12]
  2. Fundamental Research Funds for the Central Universities [HIT. NSRIF. 2014128]
  3. Subject Development Foundation of Harbin Institute of Technology (Weihai) [WH20150208]

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Photoelectrocatalytic reduction of aqueous perchlorate using Ag nanoparticles loaded TiO2 nanotube arrays (Ag-TNTs) in the presence of a hole scavenger (citric acid, Cit) under UV light irradiation was investigated in this study. TiO2 nanotube arrays (This) were prepared by anodic oxidation and Ag nanoparticles were loaded on TNTs by photodeposition. Ag-TNTs were characterized by X-ray diffraction, scanning electron microscope and X-ray photoelectron spectroscopy. The influences of Ag doping content, photogenerated electron, photogenerated hole, hydroxyl radical, initial pH and applied voltages on photoelectrocatalytic perchlorate reduction were studied and the optimum reaction conditions were determined. Results indicated that Ag-TNTs have the best photoelectrocatalytic activity when the nominal mass ratio of Ag to TiO2 is 0.84%. With an initial perchlorate concentration of 0.001 mM, the perchlorate reduction efficiency can reach 62% in the presence of Cit (0.15 mM) after 6 h reaction (368 +/- 0.5 K) at applied voltage of 1.5 V. (C) 2016 Elsevier B.V. All rights reserved.

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